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Negative electron affinities can be used in those cases where electron capture requires energy, i.e. when capture can occur only if the impinging electron has a kinetic energy large enough to excite a resonance of the atom-plus-electron system. Conversely electron removal from the anion formed in this way releases energy, which is carried out ...
It has the highest electron affinity and the one of highest electronegativity of all the elements; thus chlorine is a strong oxidizing agent. The most common compound of chlorine, sodium chloride ( table salt ), has been known since ancient times; however, around 1630, chlorine gas was obtained by the Belgian chemist and physician Jan Baptist ...
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.
The UueF molecule is expected to have a significant covalent character owing to the high electron affinity of ununennium. The bonding in UueF is predominantly between a 7p orbital on ununennium and a 2p orbital on fluorine, with lesser contributions from the 2s orbital of fluorine and the 8s, 6d z 2, and the two other 7p orbitals of ununennium.
It also has a high electron affinity, second only to chlorine, [17] and tends to capture an electron to become isoelectronic with the noble gas neon; [3] it has the highest electronegativity of any reactive element. [18] Fluorine atoms have a small covalent radius of around 60 picometers, similar to those of its period neighbors oxygen and neon.
It has also been calculated that oganesson, unlike the other noble gases, binds an electron with release of energy, or in other words, it exhibits positive electron affinity, [124] [125] due to the relativistically stabilized 8s energy level and the destabilized 7p 3/2 level, [126] whereas copernicium and flerovium are predicted to have no ...
The solid form, like chlorine, has an orthorhombic crystalline structure and is soft and easily crushed. Bromine is an insulator in all of its forms. It has a high ionisation energy (1139.9 kJ/mol), high electron affinity (324 kJ/mol), and high electronegativity (2.96). Bromine is a strong oxidising agent (Br 2 + 2e → 2HBr = 1.07 V at pH 0 ...