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The gas viscosity model of Chung et alios (1988) [5] is combination of the Chapman–Enskog(1964) kinetic theory of viscosity for dilute gases and the empirical expression of Neufeld et alios (1972) [6] for the reduced collision integral, but expanded empirical to handle polyatomic, polar and hydrogen bonding fluids over a wide temperature ...
The density is usually on the order of 1000 kg/m^3, i.e. that of water. Consequently, if a liquid has dynamic viscosity of n centiPoise, and its density is not too different from that of water, then its kinematic viscosity is around n centiStokes. For gas, the dynamic viscosity is usually in the range of 10 to 20 microPascal-seconds, or 0.01 to ...
The kinetic theory of gases allows accurate calculation of the temperature-variation of gaseous viscosity. The theoretical basis of the kinetic theory is given by the Boltzmann equation and Chapman–Enskog theory, which allow accurate statistical modeling of molecular trajectories.
Chapman–Enskog theory also predicts a simple relation between thermal conductivity, , and viscosity, , in the form =, where is the specific heat at constant volume and is a purely numerical factor. For spherically symmetric molecules, its value is predicted to be very close to 2.5 {\displaystyle 2.5} in a slightly model-dependent way.
Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. [1] For liquids, it corresponds to the informal concept of thickness; for example, syrup has a higher viscosity than water. [2]
The temperature and pressure at which ordinary solid, liquid, and gaseous water coexist in equilibrium is a triple point of water. Since 1954, this point had been used to define the base unit of temperature, the kelvin , [ 45 ] [ 46 ] but, starting in 2019 , the kelvin is now defined using the Boltzmann constant , rather than the triple point ...
He writes ′ = / for the diffusion coefficient k′, where is the osmotic pressure and k is the ratio of the frictional force to the molecular viscosity which he assumes is given by Stokes's formula for the viscosity. Introducing the ideal gas law per unit volume for the osmotic pressure, the formula becomes identical to that of Einstein's. [17]
the fluid is assumed to be isotropic, as with gases and simple liquids, and consequently is an isotropic tensor; furthermore, since the deviatoric stress tensor is symmetric, by Helmholtz decomposition it can be expressed in terms of two scalar Lamé parameters, the second viscosity and the dynamic viscosity, as it is usual in linear elasticity: