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Magnesium carbonate is ordinarily obtained by mining the mineral magnesite. Seventy percent of the world's supply is mined and prepared in China. [9] Magnesium carbonate can be prepared in laboratory by reaction between any soluble magnesium salt and sodium bicarbonate: MgCl 2 (aq) + 2 NaHCO 3 (aq) → MgCO 3 (s) + 2 NaCl(aq) + H 2 O(l) + CO 2 (g)
It is the most common cave carbonate after calcite and aragonite. [2] The mineral thermally decomposes, [5] [6] over a temperature range of approximately 220 °C to 550 °C, releasing water and carbon dioxide leaving a magnesium oxide residue. Hydromagnesite was first described in 1836 for an occurrence in Hoboken, New Jersey. [3]
Magnesite can also be formed via the carbonation of magnesium serpentine (lizardite) via the following reaction: 2 Mg 3 Si 2 O 5 (OH) 4 + 3 CO 2 → Mg 3 Si 4 O 10 (OH) 2 + 3 MgCO 3 + 3 H 2 O. However, when performing this reaction in the laboratory, the trihydrated form of magnesium carbonate (nesquehonite) will form at room temperature. [6]
Like magnesium oxide, it will generate a basic carbonate when placed in the air. [3] Magnesium sulfide can be produced by the reaction of magnesium and hydrogen sulfide, or by the reaction of magnesium sulfate and carbon disulfide at high temperature: [6] Mg + H 2 S → MgS + H 2 3 MgSO 4 + 4 CS 2 → 3 MgS + 4 COS + 4 SO 2
In chemistry, fractional crystallization is a stage-wise separation technique that relies on the liquid–solid phase change. This technique fractionates via differences in crystallization temperature and enables the purification of multi-component mixtures, as long as none of the constituents can act as solvents to the others. Due to the high ...
During the process of fractional crystallization, melts become enriched in incompatible elements. [14] Hence, knowledge of the crystallization sequence is critical in understanding how melt compositions evolve. Textures of rocks provide insights, as documented in the early 1900s by Bowen's reaction series. [15]
The carbonates bind to plumbing surfaces providing seed crystals for further crystal growth, which build up as hard scale. [citation needed] Physical water treatment (PWT) devices cause microscopic mineral crystals to form and remain suspended as they flow with the water, while also acting as seeds for further crystal growth. As water is heated ...
The first report of the hydrothermal growth of crystals [4] was by German geologist Karl Emil von Schafhäutl (1803–1890) in 1845: he grew microscopic quartz crystals in a pressure cooker. [5] In 1848, Robert Bunsen reported growing crystals of barium and strontium carbonate at 200 °C and at pressures of 15 atmospheres, using sealed glass ...