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  2. Cyclobutadiene - Wikipedia

    en.wikipedia.org/wiki/Cyclobutadiene

    The rectangular structure is consistent with the existence of two different 1,2-dideutero-1,3-cyclobutadiene valence isomers. This distortion indicates that the pi electrons are localized, in agreement with Hückel's rule which predicts that a π-system of 4 electrons is not aromatic. In principle, another situation is possible.

  3. Bicyclobutane - Wikipedia

    en.wikipedia.org/wiki/Bicyclobutane

    Bicyclo[1.1.0]butane is an organic compound with the formula C 4 H 6. It is a bicyclic molecule consisting of two cis -fused cyclopropane rings, and is a colorless and easily condensed gas. [ 1 ] Bicyclobutane is noted for being one of the most strained compounds that is isolatable on a large scale — its strain energy is estimated at 63.9 ...

  4. Hückel's rule - Wikipedia

    en.wikipedia.org/wiki/Hückel's_rule

    Hückel's rule can also be applied to molecules containing other atoms such as nitrogen or oxygen. For example pyridine (C 5 H 5 N) has a ring structure similar to benzene, except that one -CH- group is replaced by a nitrogen atom with no hydrogen. There are still six π electrons and the pyridine molecule is also aromatic and known for its ...

  5. Simple aromatic ring - Wikipedia

    en.wikipedia.org/wiki/Simple_aromatic_ring

    Many simple aromatic rings have trivial names. They are usually found as substructures of more complex molecules ("substituted aromatics"). Typical simple aromatic compounds are benzene, indole, and pyridine. [1] [2] Simple aromatic rings can be heterocyclic if they contain non-carbon ring atoms, for example, oxygen, nitrogen, or sulfur.

  6. 1,3-Dipolar cycloaddition - Wikipedia

    en.wikipedia.org/wiki/1,3-Dipolar_cycloaddition

    A 1,3-dipole is an organic molecule that can be represented as either an allyl-type or a propargyl/allenyl-type zwitterionic octet/sextet structures. Both types of 1,3-dipoles share four electrons in the π-system over three atoms. The allyl-type is bent whereas the propargyl/allenyl-type is linear in geometry.

  7. Butadiene - Wikipedia

    en.wikipedia.org/wiki/Butadiene

    1,3-Butadiene (/ ˌ b juː t ə ˈ d aɪ iː n / ⓘ) [8] is the organic compound with the formula CH 2 =CH-CH=CH 2. It is a colorless gas that is easily condensed to a liquid. It is a colorless gas that is easily condensed to a liquid.

  8. Homoaromaticity - Wikipedia

    en.wikipedia.org/wiki/Homoaromaticity

    Homoaromaticity, in organic chemistry, refers to a special case of aromaticity in which conjugation is interrupted by a single sp 3 hybridized carbon atom. Although this sp 3 center disrupts the continuous overlap of p-orbitals, traditionally thought to be a requirement for aromaticity, considerable thermodynamic stability and many of the spectroscopic, magnetic, and chemical properties ...

  9. Heterocyclic compound - Wikipedia

    en.wikipedia.org/wiki/Heterocyclic_compound

    A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s). [1] Heterocyclic organic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of organic heterocycles .

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