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  2. Aniline - Wikipedia

    en.wikipedia.org/wiki/Aniline

    Aniline reacts with acyl chlorides such as acetyl chloride to give amides. The amides formed from aniline are sometimes called anilides , for example CH 3 −C(=O)−NH−C 6 H 5 is acetanilide . At high temperatures aniline and carboxylic acids react to give the anilides.

  3. Anilide - Wikipedia

    en.wikipedia.org/wiki/Anilide

    Aniline reacts with acyl chlorides or carboxylic anhydrides to give anilides. For example, reaction of aniline with acetyl chloride provides acetanilide ( CH 3 −CO−NH−C 6 H 5 ). At high temperatures, aniline and carboxylic acids react to give anilides.

  4. Acetyl chloride - Wikipedia

    en.wikipedia.org/wiki/Acetyl_chloride

    Acetyl chloride was first prepared in 1852 by French chemist Charles Gerhardt by treating potassium acetate with phosphoryl chloride. [4]Acetyl chloride is produced in the laboratory by the reaction of acetic acid with chlorodehydrating agents such as phosphorus trichloride (PCl 3), phosphorus pentachloride (PCl 5), sulfuryl chloride (SO 2 Cl 2), phosgene, or thionyl chloride (SOCl 2).

  5. Schotten–Baumann reaction - Wikipedia

    en.wikipedia.org/wiki/Schotten–Baumann_reaction

    synthesis of benzamide from benzoyl chloride and a phenethylamine; synthesis of flutamide, a nonsteroidal antiandrogen; acylation of a benzylamine with acetyl chloride (acetic anhydride is an alternative) In the Fischer peptide synthesis (Emil Fischer, 1903), [6] an α-chloro acid chloride is condensed with the ester of an amino acid.

  6. Friedel–Crafts reaction - Wikipedia

    en.wikipedia.org/wiki/Friedel–Crafts_reaction

    The Nencki reaction (1881) is the ring acetylation of phenols with acids in the presence of zinc chloride. [24] In a green chemistry variation aluminium chloride is replaced by graphite in an alkylation of p-xylene with 2-bromobutane. This variation will not work with primary halides from which less carbocation involvement is inferred. [25]

  7. Acyl chloride - Wikipedia

    en.wikipedia.org/wiki/Acyl_chloride

    In organic chemistry, an acyl chloride (or acid chloride) is an organic compound with the functional group −C(=O)Cl. Their formula is usually written R−COCl, where R is a side chain. They are reactive derivatives of carboxylic acids (R−C(=O)OH). A specific example of an acyl chloride is acetyl chloride, CH 3 COCl.

  8. Acyl group - Wikipedia

    en.wikipedia.org/wiki/Acyl_group

    Well-known acyl compounds are the acyl chlorides, such as acetyl chloride (CH 3 COCl) and benzoyl chloride (C 6 H 5 COCl). These compounds, which are treated as sources of acylium cations, are good reagents for attaching acyl groups to various substrates.

  9. 4-Bromoaniline - Wikipedia

    en.wikipedia.org/wiki/4-bromoaniline

    4-Bromoaniline is a compound where an aniline molecule is substituted with a bromine atom on the para position. Commercially available, this compound may be used as a building block, e.g. in the preparation of monobrominated biphenyl via the Gomberg-Bachmann reaction .