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Idealized structure of lignin from a softwood. Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. [1] Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily.
Lignin confers structural integrity to plants. Lignin is so heterogeneous and so recalcitrant that its value is almost exclusively measured as a fuel. hemicellulose is composed of branched polysaccharides. A particular problem is that hemicellulose is covalently linked to lignin, usually through ferulic acid component of the
Biopolymers can be sustainable, carbon neutral and are always renewable, because they are made from plant or animal materials which can be grown indefinitely. Since these materials come from agricultural crops , their use could create a sustainable industry.
Cellulosic sugars are used as renewable resources for biochemical and biofuels industries and can be used to produce intermediates by fermentative processes. The availability of industrial sugars from renewable resources, in sufficient quantities and at a favorable cost enables the products to be cost-competitive to fossil fuel based products.
Plants are made from lignin, hemicellulose and cellulose; second-generation technology uses one, two or all of these components. Common lignocellulosic energy crops include wheat straw, Arundo donax, Miscanthus spp., short rotation coppice poplar and willow. However, each offers different opportunities and no one crop can be considered 'best ...
Torrefaction is a thermochemical treatment of biomass at 200 to 320 °C (392 to 608 °F). It is carried out under atmospheric pressure and in the absence of oxygen.During the torrefaction process, the water contained in the biomass as well as superfluous volatiles are released, and the biopolymers (cellulose, hemicellulose and lignin) partly decompose, giving off various types of volatiles. [4]
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The major constituents of natural fibers (lignocelluloses) are cellulose, hemicellulose, lignin, pectin and ash. The percentage of each component varies for each different type of fiber, however, generally, are around 60-80% cellulose, 5–20% lignin, and 20% of moisture, besides hemicellulose and a small percent of residual chemical components.
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