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Phosphorus is a key anti-wear component in motor oil and is usually found in motor oil in the form of zinc dithiophosphate (ZDDP). Each new API category has placed successively lower phosphorus and zinc limits, and thus has created a controversial issue of obsolescent oils needed for older engines, especially engines with sliding (flat/cleave ...
Zinc dithiophosphate are produced in two steps. First phosphorus pentasulfide is treated with suitable alcohols (ROH) to give the dithiophosphoric acid. A wide variety of alcohols can be employed, which allows the lipophilicity of the final zinc product to be fine tuned. The resulting dithiophosphate is then neutralized by adding zinc oxide: [7 ...
zinc dialkyl dithio phosphate (ZDDP), probably the most widely used [2] in formulated engine oils, also acts as a corrosion inhibitor and antioxidant; Tricresyl phosphate (TCP), used for high-temperature operation, often used as an AW and EP additive in turbine engine lubricants, and also in some crankcase oils and hydraulic fluids
Shell Rotella is a line of heavy-duty engine lubrication products produced by Shell plc.The line includes engine oils, gear oils and coolants. The oil carries both the American Petroleum Institute (API) diesel "C" rating as well as the API gasoline engine "S" rating.
Oil-soluble organophosphates, with or without zinc, have excellent high-pressure and antiwear properties, and provide corrosion protection especially in presence of chlorinated hydrocarbons. Zinc dialkyldithiophosphates (ZDDP) start decomposing at 130-170 °C, while the activation temperature of tricresyl phosphate (TCP) typically exceeds 200 ...
Although PTFE has been called "the slickest substance known to man", [15] [16] it would hardly do any good if it remains in the oil filter. Some mass-market engine oil additives, notably the ones containing PTFE/Teflon (e.g. Slick 50) [17] and chlorinated paraffins (e.g. Dura Lube), [18] caused a major backlash by consumers; the U.S. Federal ...
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