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Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
Recall that the relationship represented in a Davenport diagram is a relationship between three variables: P CO 2, bicarbonate concentration and pH.Thus, Fig. 7 can be thought of as a topographical map—that is, a two-dimensional representation of a three-dimensional surface—where each isopleth indicates a different partial pressure or “altitude.”
In the opposite case of a titration of acid by base, the carbonate content is similarly computed from (′) [] = ′ [], where ′ is the base-side equivalence volume (from Martell and Motekaitis). When the total CO 2 content is significant, as in natural waters and alkaline effluents, two or three inflections can be seen in the pH-volume ...
An ICE table or RICE box or RICE chart is a tabular system of keeping track of changing concentrations in an equilibrium reaction. ICE stands for initial, change, equilibrium . It is used in chemistry to keep track of the changes in amount of substance of the reactants and also organize a set of conditions that one wants to solve with. [ 1 ]
Download as PDF; Printable version ... Appearance. move to sidebar hide. Acids and bases; Acceptor number; Acid; Acid–base reaction ... Template documentation ...
Non-aqueous acid–base titrations can be carried out advantageously by thermometric means. Acid leach solutions from some copper mines can contain large quantities of Fe(III) as well as Cu(II). The "free acid" (sulfuric acid) content of these leach solutions is a critical process parameter. While thermometric titrimetry can determine the free ...
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For example, if the concentration of the conjugate base is 10 times greater than the concentration of the acid, their ratio is 10:1, and consequently the pH is pK a + 1 or pK b + 1. Conversely, if a 10-fold excess of the acid occurs with respect to the base, the ratio is 1:10 and the pH is pK a − 1 or pK b − 1.