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There are a number of exceptions and special cases that violate the above rules. Sometimes the prefix is left off the initial atom: I 2 O 5 is known as iodine pentaoxide, but it should be called diiodine pentaoxide. N 2 O 3 is called nitrogen sesquioxide (sesqui-means 1 + 1 ⁄ 2). The main oxide of phosphorus is called phosphorus pentaoxide.
Iodine pentoxide (I 2 O 5) Iodine oxides are chemical compounds of oxygen and iodine. Iodine has only two stable oxides which are isolatable in bulk, iodine tetroxide and iodine pentoxide, but a number of other oxides are formed in trace quantities or have been hypothesized to exist. The chemistry of these compounds is complicated with only a ...
Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005 is the 2005 version of Nomenclature of Inorganic Chemistry (which is informally called the Red Book). It is a collection of rules for naming inorganic compounds, as recommended by the International Union of Pure and Applied Chemistry (IUPAC).
Fresh iodine pentoxide. Iodine pentoxide is the chemical compound with the formula I 2 O 5. This iodine oxide is the anhydride of iodic acid, and one of the few iodine oxides that is stable. It is produced by dehydrating iodic acid at 200 °C in a stream of dry air: [1] 2HIO 3 → I 2 O 5 + H 2 O
When heated above 150 °C, decomposition into diiodine pentoxide can be observed: 2 I 2 O 6 → 2 I 2 O 5 + O 2. The compound is diamagnetic, which is attributed to the different oxidation numbers of the iodine atoms. [2] Structurally, the compound is iodyl periodate, an iodine(V,VII) oxide approximating IO 2 + IO 4 −. [2]
A compound with iodine(V) would be a λ 5 ‑iodane, and a hypothetical iodine(VII)‑containing compound would be a λ 7 ‑iodane. Organyl-iodine ethers, a kind of λ 3 ‑iodane, are sometimes called organic hypoiodites. Alternatively, the hypervalent iodines can be classified using neutral electron counting.
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This is an accepted version of this page This is the latest accepted revision, reviewed on 9 January 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid, black ...