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  2. Valence (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Valence_(chemistry)

    Thus, each sulfur atom is hexavalent or has valence 6, but has oxidation state +5. In the dioxygen molecule O 2, each oxygen atom has 2 valence bonds and so is divalent (valence 2), but has oxidation state 0. In acetylene H−C≡C−H, each carbon atom has 4 valence bonds (1 single bond with hydrogen atom and a triple bond with the other ...

  3. Abegg's rule - Wikipedia

    en.wikipedia.org/wiki/Abegg's_rule

    Abegg's rule is sometimes referred to as "Abegg’s law of valence and countervalence". In general, for a given chemical element (as sulfur) Abegg's rule states that the sum of the absolute value of its negative valence (such as −2 for sulfur in H 2 S and its positive valence of maximum value (as +6 for sulfur in H 2 SO 4) is often equal to 8.

  4. Hume-Rothery rules - Wikipedia

    en.wikipedia.org/wiki/Hume-Rothery_rules

    [5] [6] The solute and solvent should have similar electronegativity. [7] Valency factor: two elements should have the same valence. The greater the difference in valence between solute and solvent atoms, the lower the solubility.

  5. Sulfuric acid - Wikipedia

    en.wikipedia.org/wiki/Sulfuric_acid

    Salts of [H 3 SO 4] + have been prepared (e.g. trihydroxyoxosulfonium hexafluoroantimonate(V) [H 3 SO 4] + [SbF 6] −) using the following reaction in liquid HF: [(CH 3) 3 SiO] 2 SO 2 + 3 HF + SbF 5 → [H 3 SO 4] + [SbF 6] − + 2 (CH 3) 3 SiF. The above reaction is thermodynamically favored due to the high bond enthalpy of the Si–F bond in ...

  6. Pauling's rules - Wikipedia

    en.wikipedia.org/wiki/Pauling's_rules

    One of Pauling's examples is olivine, M 2 SiO 4, where M is a mixture of Mg 2+ at some sites and Fe 2+ at others. The structure contains distinct SiO 4 tetrahedra which do not share any oxygens (at corners, edges or faces) with each other. The lower-valence Mg 2+ and Fe 2+ cations are surrounded by polyhedra which do share oxygens.

  7. Qualitative inorganic analysis - Wikipedia

    en.wikipedia.org/wiki/Qualitative_inorganic_analysis

    According to their properties, cations are usually classified into six groups. [1] Each group has a common reagent which can be used to separate them from the solution.To obtain meaningful results, the separation must be done in the sequence specified below, as some ions of an earlier group may also react with the reagent of a later group, causing ambiguity as to which ions are present.

  8. Ammonium heptamolybdate - Wikipedia

    en.wikipedia.org/wiki/Ammonium_heptamolybdate

    Ammonium heptamolybdate is the inorganic compound whose chemical formula is (NH 4) 6 Mo 7 O 24, normally encountered as the tetrahydrate.A dihydrate is also known. It is a colorless solid, often referred to as ammonium paramolybdate or simply as ammonium molybdate, although "ammonium molybdate" can also refer to ammonium orthomolybdate, (NH 4) 2 MoO 4, and several other compounds.

  9. Oxidation state - Wikipedia

    en.wikipedia.org/wiki/Oxidation_state

    The bond-order formula at the bottom is closest to the reality of four equivalent oxygens each having a total bond order of 2. That total includes the bond of order ⁠ 1 / 2 ⁠ to the implied cation and follows the 8 − N rule [ 7 ] requiring that the main-group atom's bond-order total equals 8 − N valence electrons of the neutral atom ...