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The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
As such water percolates through calcium carbonate rock, the CaCO 3 dissolves according to one of the trends above. When that same water then emerges from the tap, in time it comes into equilibrium with CO 2 levels in the air by outgassing its excess CO 2. The calcium carbonate becomes less soluble as a result, and the excess precipitates as ...
Solubility will also depend on the excess or deficiency of a common ion in the solution [clarification needed], a phenomenon known as the common-ion effect. To a lesser extent, solubility will depend on the ionic strength of solutions. The last two effects can be quantified using the equation for solubility equilibrium.
Calcium carbonate is more soluble at lower temperatures and at higher pressures. It is also more soluble if the concentration of dissolved CO 2 is higher. Adding a reactant to the above chemical equation pushes the equilibrium towards the right producing more products: Ca 2+ and HCO 3 −, and consuming more reactants CO 2 and calcium carbonate ...
As water containing carbon dioxide (including extra CO 2 acquired from soil organisms) passes through limestone or other calcium carbonate-containing minerals, it dissolves part of the calcium carbonate, hence becomes richer in bicarbonate. As the groundwater enters the cave, the excess carbon dioxide is released from the solution of the ...
The equation Ω = [Ca 2+] X [CO 3 2-]/K' sp expresses the CaCO 3 saturation state of seawater. [4] The calcite saturation horizon is where Ω =1; dissolution proceeds slowly below this depth. The lysocline is the depth that this dissolution impacts is again notable, also known as the inflection point with sedimentary CaCO 3 versus various water ...
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.