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The reaction quotient plays a crucial role in understanding the direction and extent of a chemical reaction's progress towards equilibrium: Equilibrium condition: At equilibrium, the reaction quotient (Q) is equal to the equilibrium constant (K) for the reaction. This condition is represented as Q = K, indicating that the forward and reverse ...
The explosion of the Ivy Mike hydrogen bomb. The hydrogen bomb was the first device able to achieve fusion energy gain factor significantly larger than 1.. A fusion energy gain factor, usually expressed with the symbol Q, is the ratio of fusion power produced in a nuclear fusion reactor to the power required to maintain the plasma in steady state.
a thermodynamic equilibrium constant, denoted by , is defined to be the value of the reaction quotient Q t when forward and reverse reactions occur at the same rate. At chemical equilibrium , the chemical composition of the mixture does not change with time, and the Gibbs free energy change Δ G {\displaystyle \Delta G} for the reaction is zero.
Many host–guest complexes has 1:1 stoichiometry, but many others have more complex structures. The general equilibrium can be written as p A + q B ⇌ A p B q. The study of these complexes is important for supramolecular chemistry [24] [25] and molecular recognition.
where p 1 and p 2 are the momenta of the two atoms, and q is the deviation of the inter-atomic separation from its equilibrium value. Every degree of freedom in the energy is quadratic and, thus, should contribute 1 ⁄ 2 k B T to the total average energy, and 1 ⁄ 2 k B to the heat capacity.
In the case of chemical reactions this is usually the number of particles or mole fractions, subject to the conservation of elements. At equilibrium, these will take on their equilibrium values, and the internal energy will be a function only of the chosen value of entropy . By the definition of the Legendre transform, the Helmholtz free energy ...
In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. [1] This state results when the forward reaction proceeds at the same rate as the reverse ...
In this case, K eq can be defined as ratio of B to C rather than the equilibrium constant. When B / C > 1, B is the favored product, and the data on the Van 't Hoff plot will be in the positive region. When B / C < 1, C is the favored product, and the data on the Van 't Hoff plot will be in the negative region.