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Ruthenium(III) acetate, commonly known as basic ruthenium acetate, [1] describes a family of salts where the cation has the formula [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3] +.A representative derivative is the dihydrate of the tetrafluoroborate salt [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3]BF 4 (H 2 O) 2, which is the source of the data in the table above. [2]
Indium acetate is an acetate of indium, with the chemical formula In(CH 3 COO) 3. It is soluble in water, acetic acid and mineral acids. [ 1 ] It is the precursor of indium-containing compounds such as the solar cell materials CuInS 2 [ 2 ] and indium phosphide quantum dots .
3 in hydrochloric acid, is often used as a starting material for the synthesis of other Ir(III) compounds. [2] Another compound used as a starting material is ammonium hexachloroiridate(III), (NH 4) 3 IrCl 6. In the presence of air, iridium metal dissolves in molten alkali-metal cyanides to produce the Ir(CN) 3− 6 (hexacyanoiridate) ion.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
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Applications include their use as NMR "shift reagents" and as catalysts for organic synthesis, and precursors to industrial hydroformylation catalysts. C 5 H 7 O − 2 in some cases also binds to metals through the central carbon atom; this bonding mode is more common for the third-row transition metals such as platinum(II) and iridium(III).