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Vanadium(III) oxide is the inorganic compound with the formula V 2 O 3.It is a black solid prepared by reduction of V 2 O 5 with hydrogen or carbon monoxide. [3] [4] It is a basic oxide dissolving in acids to give solutions of vanadium (III) complexes. [4]
From left: [V(H 2 O) 6] 2+ (lilac), [V(H 2 O) 6] 3+ (green), [VO(H 2 O) 5] 2+ (blue) and [VO(H 2 O) 5] 3+ (yellow).. Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements, niobium and tantalum, are somewhat more limited to ...
Vanadium(II) oxide is the inorganic compound with the idealized formula VO. It is one of the several binary vanadium oxides.It adopts a distorted NaCl structure and contains weak V−V metal to metal bonds.
Additionally a range of polyoxovanadate ions exist which include discrete ions and "infinite" polymeric ions. [2] There are also vanadates, such as rhodium vanadate, RhVO 4 , which has a statistical rutile structure where the Rh 3+ and V 5+ ions randomly occupy the Ti 4+ positions in the rutile lattice, [ 3 ] that do not contain a lattice of ...
In chemistry, ion association is a chemical reaction whereby ions of opposite electric charge come together in solution to form a distinct chemical entity. [1] [2] Ion associates are classified, according to the number of ions that associate with each other, as ion pairs, ion triplets, etc. Ion pairs are also classified according to the nature of the interaction as contact, solvent-shared or ...
These solutions contain mainly the ions HVO 4 2− and V 2 O 7 4− between pH 9 and pH 13, but below pH 9 more exotic species such as V 4 O 12 4− and HV 10 O 28 5− (decavanadate) predominate. Upon treatment with thionyl chloride, it converts to the volatile liquid vanadium oxychloride, VOCl 3: [11] V 2 O 5 + 3 SOCl 2 → 2 VOCl 3 + 3 SO 2
In condensed matter physics and inorganic chemistry, the cation-anion radius ratio can be used to predict the crystal structure of an ionic compound based on the relative size of its atoms. It is defined as the ratio of the ionic radius of the positively charged cation to the ionic radius of the negatively charged anion in a cation-anion compound.
Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice.