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High-pressure chemistry is concerned with those chemical processes that are carried out under high pressure – pressures in the thousands of bars (100 kPa) or higher.High-pressure processes are generally faster and have a higher conversion efficiency than processes at ambient pressure.
In science and engineering the study of high pressure examines its effects on materials and the design and construction of devices, such as a diamond anvil cell, which can create high pressure. High pressure usually means pressures of thousands (kilo bars ) or millions (megabars) of times atmospheric pressure (about 1 bar or 100,000 Pa).
High-performance liquid chromatography (HPLC), formerly referred to as high-pressure liquid chromatography, is a technique in analytical chemistry used to separate, identify, and quantify specific components in mixtures.
The equipment used for pressure experiments depends on whether the pressure is to be increased or decreased and by how much. A vacuum pump is used to remove the air out of a vacuum vessel for low-pressure experiments. High-pressures can be created with a piston-cylinder apparatus, up to 5 GPa (50 000 bar) and ~2000 °C.
The pressure referred to is the partial pressure of the substance, not the total (e.g. atmospheric) pressure of the entire system. Thus, any solid can sublime if its vapour pressure is higher than the surrounding partial pressure of the same substance, and in some cases, sublimation occurs at an appreciable rate (e.g. water ice just below 0 °C).
At a given temperature and pressure, a substance with high volatility is more likely to exist as a vapour, while a substance with low volatility is more likely to be a liquid or solid. Volatility can also describe the tendency of a vapor to condense into a liquid or solid; less volatile substances will more readily condense from a vapor than ...
When these fluctuations were explained as a manifestation of changes in atmospheric pressure, the science of meteorology was born. Over time, 760 millimeters of mercury at 0 °C came to be regarded as the standard atmospheric pressure. In honour of Torricelli, the torr was defined as a unit of pressure equal to one millimeter of mercury at 0 °C.
For gases, pressure is sometimes measured not as an absolute pressure, but relative to atmospheric pressure; such measurements are called gauge pressure. An example of this is the air pressure in an automobile tire, which might be said to be "220 kPa (32 psi)", but is actually 220 kPa (32 psi) above atmospheric pressure. Since atmospheric ...