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In chemistry, an alcohol (from the Arabic word al-kuḥl, الكحل) is a type of organic compound that carries at least one hydroxyl (−OH) functional group bound to a saturated carbon atom. [ 2 ][ 3 ] Alcohols range from the simple, like methanol and ethanol, to complex, like sugars and cholesterol. The presence of an OH group strongly ...
Ethanol fermentation, also called alcoholic fermentation, is a biological process which converts sugars such as glucose, fructose, and sucrose into cellular energy, producing ethanol and carbon dioxide as by-products. Because yeasts perform this conversion in the absence of oxygen, alcoholic fermentation is considered an anaerobic process.
Lucas' reagent. "Lucas' reagent" is a solution of anhydrous zinc chloride in concentrated hydrochloric acid. This solution is used to classify alcohols of low molecular weight. The reaction is a substitution in which the chloride replaces a hydroxyl group. A positive test is indicated by a change from clear and colourless to turbid, signalling ...
Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.
Solvolysis. In chemistry, solvolysis is a type of nucleophilic substitution (S N 1/S N 2) or elimination where the nucleophile is a solvent molecule. [ 1 ] Characteristic of S N 1 reactions, solvolysis of a chiral reactant affords the racemate. Sometimes however, the stereochemical course is complicated by intimate ion pairs, whereby the ...
N,N′-Dicyclohexylcarbodiimide (DCC or DCCD)[1] is an organic compound with the chemical formula (C 6 H 11 N) 2 C. It is a waxy white solid with a sweet odor. Its primary use is to couple amino acids during artificial peptide synthesis. The low melting point of this material allows it to be melted for easy handling.
Carbonyl reduction. Oxidation ladders such as this one are used to illustrate sequences of carbonyls which can be interconverted through oxidations or reductions. In organic chemistry, carbonyl reduction is the conversion of any carbonyl group, usually to an alcohol. It is a common transformation that is practiced in many ways. [1]
A remarkable feature of these reactions is the ability to conduct carbonyl allylation from the alcohol oxidation state. Due to a kinetic preference for primary alcohol dehydrogenation, diols containing both primary and secondary alcohols undergo site-selective carbonyl allylation at the primary alcohol without the need for protecting groups. [18]