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4-tert-Butylbenzaldehyde is notable as a rare example of industrial-scale electrochemistry. It is produced by BASF and Givaudan (typically as its methanol acetal) through a double anodic oxidation of 4-tert-butyltoluene on greater than 10,000 ton per year scale. [2] [3]
Industrial synthesis of bourgeonal involves a mixed aldol reaction of 4-tert-butylbenzaldehyde and acetaldehyde, followed by hydrogenation. Alternatively it may be produced by the alkylation of tert-butylbenzene with propanal (often in its acetal form). [1]
Lilial is produced by the mixed aldol coupling of 4-tert-butylbenzaldehyde (typically as it's methanol acetal) and propionaldehyde, followed by hydrogenation.
4-tert-Butylbenzaldehyde; N-tert-Butylbenzenesulfinimidoyl chloride; Para-tert-Butylbenzoic acid; 4-tert-Butylcatechol; Tert-Butyldiphenylsilyl; Tert-Butylhydroquinone;
4-Bromobenzaldehyde; 4-tert-Butylbenzaldehyde; C. 2-Carboxybenzaldehyde; ... Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; ...
4-tert-Butylbenzaldehyde; para-tert-Butylbenzoic acid; Methyl eugenol; Methyl isoeugenol; 2-Phenethyl propionate; Wieland–Miescher ketone
4-tert-butylbenzaldehyde; Metadata. This file contains additional information, probably added from the digital camera or scanner used to create or digitize it.
Firstly, 2,4-dimethyl-6-tert-butylphenol is reacted with formaldehyde and HCl (Blanc reaction) to generate a chloromethyl group in the less hindered meta position. This intermediate then reacts with cyanuric acid to give the desired product.