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The chromate and dichromate ions are fairly strong oxidizing agents. Commonly three electrons are added to a chromium atom, reducing it to oxidation state +3. In acid solution the aquated Cr 3+ ion is produced. Cr 2 O 2− 7 + 14 H + + 6 e − → 2 Cr 3+ + 7 H 2 O ε 0 = 1.33 V. In alkaline solution chromium(III) hydroxide is produced.
Chattem announced that on November 1, 2005, they would introduce a new line of shampoos under the brand name Selsun Salon. These contained a different active ingredient than Selsun Blue, pyrithione zinc 1%, and are oriented toward the higher-end shampoo market. Other active ingredients such as salicylic acid and botanicals are in other versions ...
Vosene shampoo is available in four varieties: Original Medicated, Frequent Anti-Dandruff, 2 in 1 Gentle Action and Activating Shampoo. The Original formula contains salicylic acid, an anti-dandruff ingredient. However, this was not the active ingredient prior to the late 1980s.
[3] The second family of reagents are salts, featuring the pyridinium cation (C 5 H 5 NH +). pyridinium dichromate (PDC) is the pyridium salt of dichromate, [Cr 2 O 7] 2-. pyridinium chlorochromate (PCC) is the pyridinium salt of [CrO 3 Cl] −. These salts are less reactive, more easily handled, and more selective than Collins reagent in ...
It is the sodium salt of the conjugate base of the 4,5-bis(sulfanyl)-1,3-dithiole-2-thione. The salt is a precursor to dithiolene complexes and tetrathiafulvalenes. [1] Reduction of carbon disulfide with sodium affords sodium 1,3-dithiole-2-thione-4,5-dithiolate together with sodium trithiocarbonate: 4 Na + 4 CS 2 → Na 2 C 3 S 5 + Na 2 CS 3
The structure of nickel chromate is the same as for chromium vanadate, CrVO 4. Crystals have an orthorhombic structure with unit cell sizes a = 5.482 Å, b = 8.237 Å, c = 6.147 Å. The cell volume is 277.6 Å 3 with four formula per unit cell. [5] [7] Nickel chromate is dark in colour, unlike most other chromates which are yellow. [3]
Furthermore, the dichromate can be protonated: [HCr 2 O 7] − ⇌ [Cr 2 O 7] 2− + H +, pK a = 1.8 [6] Loss of the second proton occurs in the pH range 4–8, making the ion [HCrO 4] − a weak acid. [citation needed] Molecular chromic acid could in principle be made by adding chromium trioxide to water (cf. manufacture of sulfuric acid). CrO ...
[3] [4] In 1896 the German chemist Raphael E. Liesegang noted the phenomenon when he dropped a solution of silver nitrate onto a thin layer of gel containing potassium dichromate. After a few hours, sharp concentric rings of insoluble silver dichromate formed. It has aroused the curiosity of chemists for many years.
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