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Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as 101,325 Pa (1,013.25 hPa), which is equivalent to 1,013.25 millibars, [1] 760 mm Hg, 29.9212 inches Hg, or 14.696 psi. [2]
Antoine equation. The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine [fr] (1825–1897).
Pressure as a function of the height above the sea level. There are two equations for computing pressure as a function of height. The first equation is applicable to the atmospheric layers in which the temperature is assumed to vary with altitude at a non null lapse rate of : = [,, ()] ′, The second equation is applicable to the atmospheric layers in which the temperature is assumed not to ...
Since 1982, STP has been defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 10 5 Pa (100 kPa, 1 bar). NIST uses a temperature of 20 °C (293.15 K, 68 °F) and an absolute pressure of 1 atm (14.696 psi, 101.325 kPa). [ 3 ] This standard is also called normal temperature and pressure (abbreviated as NTP).
To accommodate the lowest points on Earth, the model starts at a base geopotential altitude of 610 meters (2,000 ft) below sea level, with standard temperature set at 19 °C. With a temperature lapse rate of −6.5 °C (-11.7 °F) per km (roughly −2 °C (-3.6 °F) per 1,000 ft), the table interpolates to the standard mean sea level values of ...
The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at 0 °C (32 °F) and standard gravity (g n = 9.806 65 m/s 2). [2] It was used as a reference condition for physical and chemical properties, and the definition of the centigrade temperature scale set 100 °C as the boiling point of water at this pressure.
The universal gas constant was apparently introduced independently by Clausius' student, A.F. Horstmann (1873) [3] [4] and Dmitri Mendeleev who reported it first on 12 September 1874. [5] Using his extensive measurements of the properties of gases, [ 6 ] [ 7 ] Mendeleev also calculated it with high precision, within 0.3% of its modern value.
The atmospheric pressure is roughly equal to the sum of partial pressures of constituent gases – oxygen, nitrogen, argon, water vapor, carbon dioxide, etc.. In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. [1]