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  2. Charge-transfer complex - Wikipedia

    en.wikipedia.org/wiki/Charge-transfer_complex

    In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...

  3. Template:Organic reactions - Wikipedia

    en.wikipedia.org/wiki/Template:Organic_reactions

    Main page; Contents; Current events; Random article; About Wikipedia; Contact us

  4. Charge transfer coefficient - Wikipedia

    en.wikipedia.org/wiki/Charge_transfer_coefficient

    They appear in the Butler–Volmer equation and related expressions. The symmetry factor and the charge transfer coefficient are dimensionless. [1] According to an IUPAC definition, [2] for a reaction with a single rate-determining step, the charge transfer coefficient for a cathodic reaction (the cathodic transfer coefficient, α c) is defined as:

  5. Cross-coupling reaction - Wikipedia

    en.wikipedia.org/wiki/Cross-coupling_reaction

    The leaving group X in the organic partner is usually a halide, although triflate, tosylate, pivalate esters, and other pseudohalides have been used. [15] Chloride is an ideal group due to the low cost of organochlorine compounds. Frequently, however, C–Cl bonds are too inert, and bromide or iodide leaving groups are required for acceptable ...

  6. Knoevenagel condensation - Wikipedia

    en.wikipedia.org/wiki/Knoevenagel_condensation

    The resulting enone 3 is a charge transfer complex molecule. A knoevenagel condensation. The Knoevenagel condensation is a key step in the commercial production of the antimalarial drug lumefantrine (a component of Coartem): [8] Final step in Lumefantrine synthesis

  7. Rearrangement reaction - Wikipedia

    en.wikipedia.org/wiki/Rearrangement_reaction

    In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...

  8. Organic semiconductor - Wikipedia

    en.wikipedia.org/wiki/Organic_semiconductor

    In the 1950s, researchers discovered that polycyclic aromatic compounds formed semi-conducting charge-transfer complex salts with halogens. In particular, high conductivity of 0.12 S/cm was reported in perylene–iodine complex in 1954. [3] This finding indicated that organic compounds could carry current.

  9. Marcus theory - Wikipedia

    en.wikipedia.org/wiki/Marcus_theory

    The abscissa is the transferred amount of charge Δe or the induced polarization P, the ordinate the Gibbs free energy. ΔG(0) ‡ = λ o /4 is the reorganization energy at Δe = 0.5, it corresponds to the activation energy of the self-exchange reaction. Of course, in this classical model the transfer of any arbitrary amount of charge Δe is ...

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