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One classic reaction is the Chichibabin reaction (Aleksei Chichibabin, 1914) in which pyridine is reacted with an alkali-metal amide such as sodium amide to form 2-aminopyridine. [ 6 ] In the compound methyl 3-nitropyridine-4-carboxylate, the meta nitro group is actually displaced by fluorine with cesium fluoride in DMSO at 120 °C.
This is a list of historically significant items found by metal detecting method, only excluding magnet fishing finds, since magnet fishing is usually considered a distinctively different and separate hobby from traditional metal detecting.
The terminology is typically applied to organometallic and coordination complexes, but resembles the Sn2 mechanism in organic chemistry. The opposite pathway is dissociative substitution, being analogous to the Sn1 pathway. Intermediate pathways exist between the pure associative and pure dissociative pathways, these are called interchange ...
Low-background steel, also known as pre-war steel [1] and pre-atomic steel, [2] is any steel produced prior to the detonation of the first nuclear bombs in the 1940s and 1950s. Typically sourced from ships (either as part of regular scrapping or shipwrecks ) and other steel artifacts of this era, it is often used for modern particle detectors ...
Competition experiment between SN2 and E2. With ethyl bromide, the reaction product is predominantly the substitution product. As steric hindrance around the electrophilic center increases, as with isobutyl bromide, substitution is disfavored and elimination is the predominant reaction. Other factors favoring elimination are the strength of the ...
The 46 metal plates carry the voltages which set up the potential gradient. The kinetic energy distribution in the direction of ion flight can be corrected by using a reflectron. [7] [8] The reflectron uses a constant electrostatic field to reflect the ion beam toward the detector. The more energetic ions penetrate deeper into the reflectron ...
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