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Alternatively, HCl can be generated by the reaction of sulfuric acid with sodium chloride: [17] NaCl + H 2 SO 4 → NaHSO 4 + HCl↑. This reaction occurs at room temperature. Provided there is NaCl remaining in the generator and it is heated above 200 °C, the reaction proceeds further: NaCl + NaHSO 4 → Na 2 SO 4 + HCl↑
In neutralization reactions, basic oxides reacts with an acid to form salt and water: Magnesium oxide reacts with hydrogen chloride (acid) to produce magnesium chloride (salt) and water: MgO + 2 HCl → MgCl 2 + H 2 O; Sodium oxide reacts with hydrogen chloride (acid) to produce sodium chloride (salt) and water: Na 2 O + 2 HCl → 2 NaCl + H 2 O
To ensure that these do not contaminate the precipitated salt, it is important to ensure they do not also precipitate. [11] If the two solutions have hydrogen ions and hydroxide ions as the counterions, they will react with one another in what is called an acid–base reaction or a neutralization reaction to form water. [12]
View of one slab of hydrohalite, NaCl·2H 2 O. (red = O, white = H, green = Cl, purple = Na). [28] From cold (sub-freezing) solutions, salt crystallises with water of hydration as hydrohalite (the dihydrate NaCl·2 H 2 O). [29] In 2023, it was discovered that under pressure, sodium chloride can form the hydrates NaCl·8.5H 2 O and NaCl·13H 2 O ...
Sodium chlorate can be used with hydrochloric acid (or also sulfuric acid and sodium chloride, the reaction of which generates HCl) to chlorinate aromatic compounds without the use of organic solvents. In this case its function is to oxidize the HCl to obtain either HOCl or Cl 2 (depending upon the pH) in-situ which are the active chlorinating ...
For example, hydrochloric acid, HCl, is a strong acid. HCl(aq) → H + (aq) + Cl − (aq) A strong base is one that is fully dissociated in aqueous solution. For example, sodium hydroxide, NaOH, is a strong base. NaOH(aq) → Na + (aq) + OH − (aq) Therefore, when a strong acid reacts with a strong base the neutralization reaction can be ...
In terms of its acid–base properties, chloride is a weak base as indicated by the negative value of the pK a of hydrochloric acid. Chloride can be protonated by strong acids, such as sulfuric acid: NaCl + H 2 SO 4 → NaHSO 4 + HCl. Ionic chloride salts react with other salts to exchange anions.
The process involves intermediate formation of sodium bisulfate, an exothermic reaction that occurs at room temperature: NaCl + H 2 SO 4 → HCl + NaHSO 4. The second step of the process is endothermic, requiring energy input: NaCl + NaHSO 4 → HCl + Na 2 SO 4. Temperatures in the range 600-700 °C are required. [5]