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Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F), produced as volatile derivatives of methane, ethane, and propane. The most common example is dichlorodifluoromethane (R-12). R-12 is also commonly called Freon and ...
Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. [4] Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond (compared to carbon-hydrogen bonds) through favorable covalent ...
The carbon–fluorine bond of the smaller molecules is formed in three principal ways: Fluorine replaces a halogen or hydrogen, or adds across a multiple bond. The direct reaction of hydrocarbons with fluorine gas can be dangerously reactive, so the temperature may need to be lowered even to −150 °C (−240 °F). [115] "
By contrast, the heavier halogens are far less reactive toward saturated hydrocarbons. Highly specialised conditions and apparatus are required for fluorinations with elemental fluorine. Commonly, fluorination reagents are employed instead of F 2. Such reagents include cobalt trifluoride, chlorine trifluoride, and iodine pentafluoride. [4]
Chlorine is the second halogen, being a nonmetal in group 17 of the periodic table. Its properties are thus similar to fluorine, bromine, and iodine, and are largely intermediate between those of the first two. Chlorine has the electron configuration [Ne]3s 2 3p 5, with the seven electrons in the third and outermost shell acting as its valence ...
Fluorocarbons with few C–F bonds behave similarly to the parent hydrocarbons, but their reactivity can be altered significantly.For example, both uracil and 5-fluorouracil are colourless, high-melting crystalline solids, but the latter is a potent anti-cancer drug.
Any other atoms attached to the carbons are assumed to be chlorine atoms. For example, R-22 has one carbon atom, one hydrogen atom (2−1 = 1), two fluorine atoms, and one chlorine atom (4−2−1 = 1), so it is chlorodifluoromethane , while R-134 has two carbon atoms (2−1 = 1), two hydrogen atoms (3−1 = 2), four fluorine atoms, and no ...
Saturated hydrocarbons react with chlorine and fluorine. In the case of chlorination, one of the chlorine atoms replaces a hydrogen atom. The reactions proceed via free-radical pathways, in which the halogen first dissociates into a two neutral radical atoms (homolytic fission). CH 4 + Cl 2 → CH 3 Cl + HCl CH 3 Cl + Cl 2 → CH 2 Cl 2 + HCl
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