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  2. Mole fraction - Wikipedia

    en.wikipedia.org/wiki/Mole_fraction

    In chemistry, the mole fraction or molar fraction, also called mole proportion or molar proportion, is a quantity defined as the ratio between the amount of a constituent substance, ni (expressed in unit of moles, symbol mol), and the total amount of all constituents in a mixture, ntot (also expressed in moles): [1] It is denoted xi (lowercase ...

  3. Raoult's law - Wikipedia

    en.wikipedia.org/wiki/Raoult's_law

    Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.

  4. Gibbs–Duhem equation - Wikipedia

    en.wikipedia.org/wiki/Gibbs–Duhem_equation

    In thermodynamics, the Gibbs–Duhem equation describes the relationship between changes in chemical potential for components in a thermodynamic system: [1] where is the number of moles of component the infinitesimal increase in chemical potential for this component, the entropy, the absolute temperature, volume and the pressure. is the number ...

  5. Mass fraction (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Mass_fraction_(chemistry)

    In chemistry, the mass fraction of a substance within a mixture is the ratio (alternatively denoted ) of the mass of that substance to the total mass of the mixture. [1] Expressed as a formula, the mass fraction is: tot {\displaystyle w_ {i}= {\frac {m_ {i}} {m_ {\text {tot}}}}.} Because the individual masses of the ingredients of a mixture sum ...

  6. Phase rule - Wikipedia

    en.wikipedia.org/wiki/Phase_rule

    Phase rule. In thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure (p), volume (V) and temperature (T), in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then.

  7. Flory–Huggins solution theory - Wikipedia

    en.wikipedia.org/wiki/Flory–Huggins_solution...

    Mixture of polymers and solvent on a lattice. Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing. The result is an equation for the Gibbs free energy change for mixing a polymer ...

  8. Amagat's law - Wikipedia

    en.wikipedia.org/wiki/Amagat's_law

    Overview. Amagat's law states that the extensive volume V = Nv of a gas mixture is equal to the sum of volumes Vi of the K component gases, if the temperature T and the pressure p remain the same: [1][2] N v ∑ {\displaystyle N\,v (T,p)=\sum _ {i=1}^ {K}N_ {i}\,v_ {i} (T,p).} This is the experimental expression of volume as an extensive ...

  9. Lever rule - Wikipedia

    en.wikipedia.org/wiki/Lever_rule

    Lever rule. In chemistry, the lever rule is a formula used to determine the mole fraction (xi) or the mass fraction (wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.

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