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Trimethyl phosphate is a mild methylating agent, useful for dimethylation of anilines and related heterocyclic compounds. [2] The method is complementary to the traditional Eschweiler-Clarke reaction in cases where formaldehyde engages in side reactions.
As a ligand, trimethyl phosphite has a smaller cone angle and better acceptor properties relative to trimethylphosphine. A representative derivative is the colorless tetrahedral complex Ni(P(OMe) 3) 4 (m.p. 108 °C). [4] The tridentate ligand called the Kläui ligand is derived from trimethyl phosphite. The formation of this ligand illustrates ...
It is under supervision of Bangladesh Chemical Industries Corporation (BCIC). It primarily produces phosphate fertilizers . [ 1 ] [ 2 ] The factory complex consists of 2 units of TSP fertilizer producing facility with installed capacity of 1,52,000 MT (Unit-1; 32,000 MT and Unit-2; 1,20,000 MT).
Trimethylphosphine is a highly basic ligand that forms complexes with most metals. As a ligand, trimethylphosphine's Tolman cone angle is 118°. [7] This angle is an indication of the amount of steric protection that this ligand provides to the metal that to which it is bound.
Tris(trimethylsilyl)phosphine is prepared by treating trimethylsilyl chloride, white phosphorus, and sodium-potassium alloy: [2] 1/4 P 4 + 3 Me 3 SiCl + 3 K → P(SiMe 3) 3 + 3 KCl
Dimethyl methylphosphonate can be prepared from trimethyl phosphite and a halomethane (e.g. iodomethane) via the Michaelis–Arbuzov reaction. [2]Dimethyl methylphosphonate is a schedule 2 chemical as it may be used in the production of chemical weapons.
Phosphites are oxidized to phosphate esters: P(OR) 3 + [O] → OP(OR) 3. This reaction underpins the commercial use of some phosphite esters as stabilizers in polymers. [6] Alkyl phosphite esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates.
Triethyl phosphite (TEP) is an organophosphorus compound, specifically a phosphite ester, with the formula P(OCH 2 CH 3) 3, often abbreviated P(OEt) 3.It is a colorless, malodorous liquid.