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The plaster is not pure plaster of Paris, but rather has additives to improve green strength, dry strength, permeability, and castability.For instance, talc or magnesium oxide are added to prevent cracking and reduce setting time; lime and cement limit expansion during baking; glass fibers increase strength; sand can be used as a filler. [1]
With judicious heating, gypsum converts to the partially dehydrated mineral called bassanite or plaster of Paris. This material has the formula CaSO 4 ·(nH 2 O), where 0.5 ≤ n ≤ 0.8. [8] Temperatures between 100 and 150 °C (212–302 °F) are required to drive off the water within its structure.
A gypsum block is made of gypsum plaster and water. The manufacturing process [1] is automated at production plants where raw gypsum (CaSO 4 ·2H 2 O) is ground and dried, then heated to remove three-quarters of the bound water and thus transformed into calcium sulfate hemihydrate (CaSO 4 ·½H 2 O), also known as gypsum plaster, stucco, calcined gypsum or plaster of Paris.
When the dry plaster powder is mixed with water, it rehydrates over time into gypsum. The setting of plaster slurry starts about 10 minutes after mixing and is complete in about 45 minutes. The setting of plaster of Paris is accompanied by a slight expansion of volume. It is used in making casts for statues, toys, and more. [19]
The word gypsum is derived from the Greek word γύψος (gypsos), "plaster". [9] Because the quarries of the Montmartre district of Paris have long furnished burnt gypsum (calcined gypsum) used for various purposes, this dehydrated gypsum became known as plaster of Paris. Upon adding water, after a few dozen minutes, plaster of Paris becomes ...
Gypsum mortar, also called plaster of Paris, was used in the construction of many ancient structures. It is made from gypsum, which requires a lower firing temperature. It is therefore easier to make than lime mortar and sets up much faster, which may be a reason it was used as the typical mortar in ancient, brick arch and vault construction.
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Slowing the set time of plaster of Paris products (most widely used in gypsum plaster wall work and artwork casting) is typically achieved by the simple introduction of almost any acid diluted into the mixing water. A commercial retardant premix additive sold by USG to trade interior plasterers includes at least 40% potassium bitartrate.