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[2] [3] Tantalum boride films can be deposited from a gas mixture of TaCl 5-BCl 3-H 2-Ar in the temperature range 540–800 °C. TaB 2 (single-phase) is deposited at a source gas flow ratio (BCl 3 /TaCl 5) of six and a temperature above 600 °C. TaB (single-phase) is deposited at BCl 3 /TaCl 5 = 2–4 and T = 600–700 °C. [1]
Tantalum halides span the oxidation states of +5, +4, and +3. Tantalum pentafluoride (TaF 5) is a white solid with a melting point of 97.0 °C. The anion [TaF 7] 2-is used for its separation from niobium. [41] The chloride TaCl 5, which exists as a dimer, is the main reagent in synthesis of new Ta compounds. It hydrolyzes readily to an oxychloride.
[4] 2 Ta + 5 Cl 2 → 2 TaCl 5 2 Ta + 10 HCl → 2 TaCl 5 + 5 H 2. It can also be prepared by a reaction between tantalum pentoxide and thionyl chloride at 240 °C Ta 2 O 5 + 5 SOCl 2 → 2 TaCl 5 + 5 SO 2. Tantalum pentachloride is commercially available, however samples can be contaminated with tantalum(V) oxychloride (TaOCl 3), formed by ...
Tantalum ores often contain significant amounts of niobium, which is itself a valuable metal.As such, both metals are extracted so that they may be sold. The overall process is one of hydrometallurgy and begins with a leaching step; in which the ore is treated with hydrofluoric acid and sulfuric acid to produce water-soluble hydrogen fluorides, such as the heptafluorotantalate.
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.
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2 H 2 [NbOF 5] + 10 NH 4 OH → Nb 2 O 5 ↓ + 10 NH 4 F + 7 H 2 O. Several methods are used for the reduction to metallic niobium. The electrolysis of a molten mixture of K 2 [NbOF 5] and sodium chloride is one; the other is the reduction of the fluoride with sodium. With this method, a relatively high purity niobium can be obtained.