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Thermal inertia is less directly comparable to the mass-and-velocity term used in mechanics, where inertia restricts the acceleration of an object. In a similar way, thermal inertia can be a measure of heat capacity of a mass, and of the velocity of the thermal wave which controls the surface temperature of a material.
Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer P = / W ML 2 T −3: Thermal intensity I = / W⋅m −2: MT −3: Thermal/heat flux density (vector analogue of thermal intensity above) q
kT (also written as k B T) is the product of the Boltzmann constant, k (or k B), and the temperature, T.This product is used in physics as a scale factor for energy values in molecular-scale systems (sometimes it is used as a unit of energy), as the rates and frequencies of many processes and phenomena depend not on their energy alone, but on the ratio of that energy and kT, that is, on E ...
The laws of thermodynamics imply the following relations between these two heat capacities (Gaskell 2003:23): = = Here is the thermal expansion coefficient: = is the isothermal compressibility (the inverse of the bulk modulus):
Thermochemistry rests on two generalizations. Stated in modern terms, they are as follows: [1] Lavoisier and Laplace's law (1780): The energy change accompanying any transformation is equal and opposite to energy change accompanying the reverse process.
Temperature gradients, thermal expansion or contraction and thermal shocks are things that can lead to thermal stress. This type of stress is highly dependent on the thermal expansion coefficient which varies from material to material. In general, the greater the temperature change, the higher the level of stress that can occur.
An isothermal process is a type of thermodynamic process in which the temperature T of a system remains constant: ΔT = 0. This typically occurs when a system is in contact with an outside thermal reservoir, and a change in the system occurs slowly enough to allow the system to be continuously adjusted to the temperature of the reservoir through heat exchange (see quasi-equilibrium).
A current student text on chemistry defines heat thus: "heat is the exchange of thermal energy between a system and its surroundings caused by a temperature difference." The author then explains how heat is defined or measured by calorimetry, in terms of heat capacity , specific heat capacity, molar heat capacity, and temperature.
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