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By replenishing lost electrons with electrons from the splitting of water, photosystem II provides the electrons for all of photosynthesis to occur. The hydrogen ions (protons) generated by the oxidation of water help to create a proton gradient that is used by ATP synthase to generate ATP .
The electrons are transferred to plastoquinone and two protons, generating plastoquinol, which released into the membrane as a mobile electron carrier. This is the second core process in photosynthesis. The initial stages occur within picoseconds, with an efficiency of 100%. The seemingly impossible efficiency is due to the precise positioning ...
The intermediate formed reacts with water to liberate O 2. The cobalt-polyoxometalate complex [Co 4 (H 2 O) 2 (α-PW 9 O 34) 2] 10− is highly efficient WOC. [11] Some iron complexes catalyze water oxidation. A water-soluble complex [Fe(OTf) 2 (Me 2 Pytacn)] (Pytacn=pyridine-substituted trimethyltriazacyclononane; OTf= triflate) is an ...
Adiabatic ionization is a form of ionization in which an electron is removed from or added to an atom or molecule in its lowest energy state to form an ion in its lowest energy state. [16] The Townsend discharge is a good example of the creation of positive ions and free electrons due to ion impact.
Reaction centers are present in all green plants, algae, and many bacteria.A variety in light-harvesting complexes exist across the photosynthetic species. Green plants and algae have two different types of reaction centers that are part of larger supercomplexes known as P700 in Photosystem I and P680 in Photosystem II.
Deuteron: 2 H +, D + Triton: 3 H +, T + In addition, the ions produced by the reaction of these cations with water as well as their hydrates are called hydrogen ions: Hydronium ion: H 3 O + Zundel cation: H 5 O 2 + (named for Georg Zundel) Eigen cation: H 9 O 4 + (or H 3 O + •3H 2 O) (named for Manfred Eigen)
P680 + is the strongest biological oxidizing agent known, with an estimated redox potential of ~1.3 V. [3] This makes it possible to oxidize water during oxygenic photosynthesis. P680 + recovers its lost electron by oxidizing water via the oxygen-evolving complex , which regenerates P680.
The evolution of oxygen during the light-dependent steps in photosynthesis (Hill reaction) was proposed and proven by British biochemist Robin Hill. He demonstrated that isolated chloroplasts would make oxygen (O 2) but not fix carbon dioxide (CO 2). This is evidence that the light and dark reactions occur at different sites within the cell. [1 ...
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