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For other isotopes, the isotopic mass is usually within 0.1 u of the mass number. For example, 35 Cl (17 protons and 18 neutrons) has a mass number of 35 and an isotopic mass of 34.96885. [7] The difference of the actual isotopic mass minus the mass number of an atom is known as the mass excess, [8] which for 35 Cl is –0.03115.
Atomic mass is often measured in dalton (Da) or unified atomic mass unit (u). One dalton is equal to 1 ⁄ 12 the mass of a carbon-12 atom in its natural state. Thus, the numeric value of the atomic mass when expressed in daltons has nearly the same value as the mass number.
The atomic number or nuclear charge number (symbol Z) of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons , this is equal to the proton number ( n p ) or the number of protons found in the nucleus of every atom of that element.
For example, the atomic mass constant is exactly known when expressed using the dalton (its value is exactly 1 Da), but the kilogram is not exactly known when using these units, the opposite of when expressing the same quantities using the kilogram.
Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of the nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in daltons (making a quantity called the "relative isotopic mass"), is within 1% of the ...
Each distinct atomic number therefore corresponds to a class of atom: these classes are called the chemical elements. [5] The chemical elements are what the periodic table classifies and organizes. Hydrogen is the element with atomic number 1; helium, atomic number 2; lithium, atomic number 3; and so on.
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In general, the mass number of a given nuclide differs in value slightly from its relative atomic mass, since the mass of each proton and neutron is not exactly 1 Da; since the electrons contribute a lesser share to the atomic mass as neutron number exceeds proton number; and because of the nuclear binding energy and electron binding energy ...