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The standards below are two examples of commonly used and cited publications that provide a composition for standard dry air: ISO TR 29922-2017 provides a definition for standard dry air which specifies an air molar mass of 28,965 46 ± 0,000 17 kg·kmol-1. [2] GPA 2145:2009 is published by the Gas Processors Association.
In case of air, using the perfect gas law and the standard sea-level conditions (SSL) (air density ρ 0 = 1.225 kg/m 3, temperature T 0 = 288.15 K and pressure p 0 = 101 325 Pa), we have that R air = P 0 /(ρ 0 T 0) = 287.052 874 247 J·kg −1 ·K −1. Then the molar mass of air is computed by M 0 = R/R air = 28.964 917 g/mol. [11]
Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude. The change of atmospheric pressure with altitude can be obtained from this equation: [2]
is the molecular mass of dry air, approximately 4.81 × 10 −26 in kg. [note 1], the specific gas constant for dry air, which using the values presented above would be approximately 287.050 0676 in J⋅kg −1 ⋅K −1. [note 1] Therefore:
Molecular weight (M.W.) (for molecular compounds) and formula weight (F.W.) (for non-molecular compounds), are older terms for what is now more correctly called the relative molar mass (M r). [8] This is a dimensionless quantity (i.e., a pure number, without units) equal to the molar mass divided by the molar mass constant .
The interest stems from that accurate measurements of the unit cell volume, atomic weight and mass density of a pure crystalline solid provide a direct determination of the Avogadro constant. [3] The CODATA recommended value for the molar volume of silicon is 1.205 883 199 (60) × 10 −5 m 3 ⋅mol −1, with a relative standard uncertainty of ...
= milligrams of pollutant per cubic meter of air at sea level atmospheric pressure and T: ppmv = air pollutant concentration, in parts per million by volume T = ambient temperature in K = 273. + °C 0.082057338 = Universal gas constant in L atm mol −1 K −1: M = molecular mass (or molecular weight) of the air pollutant
The average molecular weight of dry air, which can be used to calculate densities or to convert between mole fraction and mass fraction, is about 28.946 [11] or 28.964 [12] [5] g/mol. This is decreased when the air is humid. The relative concentration of gases remains constant until about 10,000 m (33,000 ft). [13]