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According to the whole number rule proposed by Francis Aston, the mass of an isotope is roughly, but not exactly, its mass number A (Z + N) times an atomic mass unit (u), plus or minus binding energy discrepancy – atomic mass unit being the modern approximation for "mass of a proton, neutron, or hydrogen atom".
For example, the relative isotopic mass of a carbon-12 atom is exactly 12. For comparison, the atomic mass of a carbon-12 atom is exactly 12 daltons. Alternately, the atomic mass of a carbon-12 atom may be expressed in any other mass units: for example, the atomic mass of a carbon-12 atom is 1.992 646 882 70 (62) × 10 −26 kg.
The atomicity of homonuclear molecule can be derived by dividing the molecular weight by the atomic weight. For example, the molecular weight of oxygen is 31.999, [ 3 ] while its atomic weight is 15.879; [ 4 ] therefore, its atomicity is approximately 2 (31.999/15.879 ≈ 2).
A chemical element, often simply called an element, is a type of atom which has a specific number of protons in its atomic nucleus (i.e., a specific atomic number, or Z). [ 1 ] The definitive visualisation of all 118 elements is the periodic table of the elements , whose history along the principles of the periodic law was one of the founding ...
In chemistry, the whole number rule states that the masses of the isotopes are whole number multiples of the mass of the hydrogen atom. [1] The rule is a modified version of Prout's hypothesis proposed in 1815, to the effect that atomic weights are multiples of the weight of the hydrogen atom. [ 2 ]
A given atom has an atomic mass approximately equal (within 1%) to its mass number times the atomic mass unit (for example the mass of a nitrogen-14 is roughly 14 Da), but this number will not be exactly an integer except (by definition) in the case of carbon-12. [67] The heaviest stable atom is lead-208, [59] with a mass of 207.976 6521 Da. [68]
[1] The standard atomic weight of a chemical element (symbol A r °(E) for element "E") is the weighted arithmetic mean of the relative isotopic masses of all isotopes of that element weighted by each isotope's abundance on Earth. For example, isotope 63 Cu (A r = 62.929) constitutes 69% of the copper on Earth, the rest being 65 Cu (A r = 64. ...
Naturally occurring elements usually occur as mixes of different isotopes; since each isotope usually occurs with a characteristic abundance, naturally occurring elements have well-defined atomic weights, defined as the average mass of a naturally occurring atom of that element. [7] All elements have multiple isotopes, variants with the same ...