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S N 2 reaction of a bromide ion with chloroethane showing the concerted nature of the reaction, the transition state and the predictable stereochemistry through Walden inversion.
Metal-ligand cooperativity (MLC) is a mode of reactivity in which a metal and ligand of a complex are both involved in the bond breaking or bond formation of a substrate during the course of a reaction.
When the overall reaction has a high degree of concertedness, the charge built-up will be modest. Scheme 5. Prins reaction mechanism. The three reaction modes open to this oxocarbenium intermediate are: in blue: capture of the carbocation by water or any suitable nucleophile through 5 to the 1,3-adduct 6.