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In telecommunications, the free-space path loss (FSPL) (also known as free-space loss, FSL) is the attenuation of radio energy between the feedpoints of two antennas that results from the combination of the receiving antenna's capture area plus the obstacle-free, line-of-sight (LoS) path through free space (usually air). [1]
The Henderson–Hasselbalch equation can be used to model these equilibria. It is important to maintain this pH of 7.4 to ensure enzymes are able to work optimally. [10] Life threatening Acidosis (a low blood pH resulting in nausea, headaches, and even coma, and convulsions) is due to a lack of functioning of enzymes at a low pH. [10]
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
A plot of the common logarithm of the reaction rate constant k versus the logarithm of the ionization constant K a for a series of acids (for example a group of substituted phenols or carboxylic acids) gives a straight line with slope α and intercept C. The Brønsted equation is a free-energy relationship.
However, since blood is buffered with carbonate at physiological pH (near 7.4), free-base amines will be rapidly converted back into their acid form. In fact, 94.19% of cocaine will exist as the acid form under equilibrium at pH=7.4, calculated using the Henderson–Hasselbalch equation assuming a pKa of 8.61.
On a log–linear plot (logarithmic scale on the y-axis), pick some fixed point (x 0, F 0), where F 0 is shorthand for F(x 0), somewhere on the straight line in the above graph, and further some other arbitrary point (x 1, F 1) on the same graph.
For example, with pH titration data, if pH is measured to 2 decimal places, the errors of log 10 β should not be much larger than 0.01. In exploratory work where the nature of the species present is not known in advance, several different chemical models may be tested and compared.
Many thermodynamic equations are expressed in terms of partial derivatives. For example, the expression for the heat capacity at constant pressure is: = which is the partial derivative of the enthalpy with respect to temperature while holding pressure constant.