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Intersystem crossing (ISC) is an isoenergetic radiationless process involving a transition between the two electronic states with different spin multiplicity. [ 1 ] Excited electrons can undergo intersystem crossing to a degenerate state with a different spin multiplicity.
Jablonski diagram indicating intersystem crossing (left) and internal conversion (right). Internal conversion is a transition from a higher to a lower electronic state in a molecule or atom. [ 1 ] It is sometimes called "radiationless de-excitation", because no photons are emitted.
A Jablonski diagram showing the excitation of molecule A to its singlet excited state (1 A*) followed by intersystem crossing to the triplet state (3 A) that relaxes to the ground state by phosphorescence. It was used to describe absorption and emission of light by fluorescents.
Which is it then: "Intersystem crossing is a radiationless process involving a..." vs "The radiative decay /.../ phosphorescence is another manifestation of intersystem crossing"? — Preceding unsigned comment added by 84.250.10.117 15:01, 20 January 2013 (UTC)
Singlet fission is a spin-allowed process, unique to molecular photophysics, whereby one singlet excited state is converted into two triplet states.The phenomenon has been observed in molecular crystals, aggregates, disordered thin films, and covalently-linked dimers, where the chromophores are oriented such that the electronic coupling between singlet and the double triplet states is large.
Entrance sign at the tunnels. Part of the tunnel complex at Củ Chu, this tunnel has been made wider and taller to accommodate tourists. The tunnels of Củ Chi (Vietnamese: Địa đạo Củ Chi) are an immense network of connecting tunnels located in the Củ Chi District of Ho Chi Minh City (Saigon), Vietnam, and are part of a much larger network of tunnels that underlie much of the country.
The Vietnamese Wikipedia initially went online in November 2002, with a front page and an article about the Internet Society.The project received little attention and did not begin to receive significant contributions until it was "restarted" in October 2003 [3] and the newer, Unicode-capable MediaWiki software was installed soon after.
A fixed link or fixed crossing is a permanent, unbroken road or rail connection across water that uses some combination of bridges, tunnels, and causeways and does not involve intermittent connections such as drawbridges or ferries. [1] A bridge–tunnel combination is commonly used for major fixed links.