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Phosphorus pentachloride, phosphorus pentabromide, and phosphorus heptabromide are ionic in the solid and liquid states; PCl 5 is formulated as PCl 4 + PCl 6 –, but in contrast, PBr 5 is formulated as PBr 4 + Br −, and PBr 7 is formulated as PBr 4 + Br 3 −. They are widely used as chlorinating and brominating agents in organic chemistry.
Phosphorus pentabromide is a reactive, yellow solid of formula P Br 5, which has the structure [PBr 4] + Br − (tetrabromophosphonium bromide) in the solid state but in the vapor phase is completely dissociated to PBr 3 and Br 2.
Phosphorus pentabromide – PBr 5; Phosphorus pentafluoride – PF 5; Phosphorus pentasulfide – P 4 S 10; Phosphorus pentoxide – P 2 O 5; Phosphorus sesquisulfide – P 4 S 3; Phosphorus tribromide – PBr 3; Phosphorus trichloride – PCl 3; Phosphorus trifluoride – PF 3; Phosphorus triiodide – PI 3; Phosphotungstic acid – H 3 PW 12 ...
sulfur tetrafluoride oxide: 13709-54-1 F 4 OW: tungsten tetrafluoride oxide: 13520-79-1 F 4 OXe: xenon tetrafluoride oxide: 13774-85-1 F 4 P 2: diphosphorus tetrafluoride: 13824-74-3 F 4 Pb: lead tetrafluoride: 7783-59-7 F 4 Pt: platinum tetrafluoride: 13455-15-7 F 4 Pu: plutonium tetrafluoride: 13709-56-3 F 4 S: sulfur tetrafluoride: 7783-60-0 ...
Furthermore, iodination of metals tends to result in lower oxidation states than chlorination or bromination; for example, rhenium metal reacts with chlorine to form rhenium hexachloride, but with bromine it forms only rhenium pentabromide and iodine can achieve only rhenium tetraiodide. [2]
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.
Phosphorus sulfides comprise a family of inorganic compounds containing only phosphorus and sulfur.These compounds have the formula P 4 S n with n ≤ 10. Two are of commercial significance, phosphorus pentasulfide (P 4 S 10), which is made on a kiloton scale for the production of other organosulfur compounds, and phosphorus sesquisulfide (P 4 S 3), used in the production of "strike anywhere ...
Phosphoryl bromide is prepared by the reaction between phosphorus pentabromide and phosphorus pentoxide: [4] [5]. 3 PBr 5 + P 2 O 5 → 5 POBr 3. It can also be prepared via the slow addition of liquid bromine to phosphorus tribromide at 0 °C, followed by the slow addition of water and vacuum distillation of the resulting slurry.