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Phosphorus pentabromide is a reactive, yellow solid of formula P Br 5, which has the structure [PBr 4] + Br − (tetrabromophosphonium bromide) in the solid state but in the vapor phase is completely dissociated to PBr 3 and Br 2.
Phosphorus pentachloride, phosphorus pentabromide, and phosphorus heptabromide are ionic in the solid and liquid states; PCl 5 is formulated as PCl 4 + PCl 6 –, but in contrast, PBr 5 is formulated as PBr 4 + Br −, and PBr 7 is formulated as PBr 4 + Br 3 −. They are widely used as chlorinating and brominating agents in organic chemistry.
Hexafluorophosphoric acid (HPF 6) is derived from phosphorus pentafluoride and hydrogen fluoride. Its conjugate base, hexafluorophosphate (PF 6 – ), is a useful non-coordinating anion . It is often used in lithium-ion batteries , where besides providing good ionic conductivity for the liquid electrolyte, it also passivates positive aluminium ...
Finally, the triiodide ion (I − 3) is also based upon a trigonal bipyramid, but the actual molecular geometry is linear with terminal iodine atoms in the two axial positions only and the three equatorial positions occupied by lone pairs of electrons (AX 2 E 3); another example of this geometry is provided by xenon difluoride, XeF 2.
Phosphonium ion Structure of PH + 4, the parent phosphonium cation. In chemistry, the term phosphonium (more obscurely: phosphinium) describes polyatomic cations with the chemical formula PR + 4 (where R is a hydrogen or an alkyl, aryl, or halide group). These cations have tetrahedral structures.
Phosphorus heptabromide is an inorganic compound with the chemical formula P Br 7. It is one of the phosphorus bromides. At normal conditions, it forms red prismatic crystals. PBr 7 can be prepared by the sublimation of a mixture of phosphorus pentabromide and bromine. [2] PBr 5 + Br 2 → PBr 7
Phosphorus pentabromide; Phosphorus tribromide This page was last edited on 30 October 2022, at 12:54 (UTC). Text is available under the Creative Commons ...
Phosphorus is a member of the pnictogens, together with nitrogen, arsenic, antimony, bismuth, and moscovium, and consequently shares properties with them. Phosphorus is an element essential to sustaining life largely through phosphates, compounds containing the phosphate ion, PO 4 3−.