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A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The time taken for an oscillation to occur is often referred to as the oscillatory period. The systems where the restoring force on a body is directly proportional to its displacement, such as the dynamics of the spring-mass system, are described mathematically by the simple harmonic oscillator and the regular periodic motion is known as simple ...
The period T is the time taken to complete one cycle of an oscillation or rotation. The frequency and the period are related by the equation [ 4 ] f = 1 T . {\displaystyle f={\frac {1}{T}}.} The term temporal frequency is used to emphasise that the frequency is characterised by the number of occurrences of a repeating event per unit time.
In practice N is set to 1 cycle and t = T = time period for 1 cycle, to obtain the more useful relation: ... Defining equation (physical chemistry)
In chemistry, a chemical oscillator is a complex mixture of reacting chemical compounds in which the concentration of one or more components exhibits periodic changes. They are a class of reactions that serve as an example of non-equilibrium thermodynamics with far-from-equilibrium behavior.
The period, the time for one complete oscillation, is given by the expression = =, which is a good approximation of the actual period when is small. Notice that in this approximation the period τ {\displaystyle \tau } is independent of the amplitude θ 0 {\displaystyle \theta _{0}} .
Time evolution of the probability distribution (and phase, shown as color) of a coherent state with |α|=3. The coherent states (also known as Glauber states) of the harmonic oscillator are special nondispersive wave packets , with minimum uncertainty σ x σ p = ℏ ⁄ 2 , whose observables ' expectation values evolve like a classical system.
An oscillator is a physical system characterized by periodic motion, such as a pendulum, tuning fork, or vibrating diatomic molecule.Mathematically speaking, the essential feature of an oscillator is that for some coordinate x of the system, a force whose magnitude depends on x will push x away from extreme values and back toward some central value x 0, causing x to oscillate between extremes.