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Sienna is lighter in shade than raw umber, which is also clay with iron oxide, but which has a significantly higher content of manganese (5 to 20 percent) making it greenish brown or dark brown in color. When heated, raw umber becomes burnt umber, a very dark brown. [8]
Raw umber (PBr7): a natural clay pigment consisting of iron oxide, manganese oxide and aluminum oxide: Fe 2 O 3 + MnO 2 + n H 2 O + SiO 2 + Al 2 O 3. When calcined (heated) it is referred to as burnt umber and has more intense colors. Raw sienna (PBr7): a naturally occurring yellow-brown pigment
Ochre is a family of earth pigments, which includes yellow ochre, red ochre, purple ochre, sienna, and umber. The major ingredient of all the ochres is iron(III) oxide-hydroxide, known as limonite, which gives them a yellow colour. A range of other minerals may also be included in the mixture: [6]: 134 Yellow ochre (Goldochre) pigment
Umber is a natural brown pigment extracted from clay containing iron, manganese, and hydroxides. [11] Umber has diverse hues, ranging from yellow-brown to reddish-brown and even green-brown. The color shade varies depending on the proportions of the components. When heated, umber becomes a more intense color and can look almost black.
Raw sienna and burnt sienna came from Siena, Italy, while raw umber and burnt umber came from Umbria. These pigments were among the easiest to synthesize, and chemists created modern colors based on the originals. These were more consistent than colors mined from the original ore bodies, but the place names remained.
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Burnt umber is made by heating raw umber, which dehydrates the iron oxides and changes them partially to the more reddish hematite. It is used for both oil and water color paint. At a hue of 9, it is classified as a red-brown. The first recorded use of burnt umber as a color name in English was in 1650. [5]
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