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In carbohydrate chemistry carbohydrate acetalisation is an organic reaction and a very effective means of providing a protecting group. The example below depicts the acetalisation reaction of D-ribose 1. With acetone or 2,2-dimethoxypropane as the acetalisation reagent the reaction is under thermodynamic reaction control and results in the ...
Since many sugars are polyhydroxy aldehydes and ketones, sugars are a rich source of acetals and ketals. Most glycosidic bonds in carbohydrates and other polysaccharides are acetal linkages. [2] Cellulose is a ubiquitous example of a polyacetal. Benzylidene acetal and acetonide as protecting groups used in research of modified sugars.
The general structure of a hemiacetal (left) and hemiketal (right). In organic chemistry, a hemiacetal is a functional group the general formula R 1 R 2 C(OH)OR, where R 1, R 2 is a hydrogen atom or an organic substituent.
A further important example of orthogonal protecting groups occurs in carbohydrate chemistry. As carbohydrates or hydroxyl groups exhibit very similar reactivities, a transformation that protects or deprotects a single hydroxy group must be possible for a successful synthesis.
Two common examples are cellulose, a main component of the cell wall in plants, and starch, a name derived from the Anglo-Saxon stercan, meaning to stiffen. [ 2 ] To name a polysaccharide composed of a single type of monosaccharide, that is a homopolysaccharide, the ending “-ose” of the monosaccharide is replaced with “-an”. [ 3 ]
For example, a recent large meta-analysis found that replacing some saturated fats with polyunsaturated fats (like seed oils) was associated with a lower reduced risk of cardiovascular disease and ...
“Adding in more protein — I tell clients to aim for around 30 grams — at breakfast paired with high fiber carbohydrates and healthy fats can help keep energy levels up all morning ...
Salicylic acid is acetylated to form aspirin. In chemistry, acetylation is an organic esterification reaction with acetic acid.It introduces an acetyl group into a chemical compound.