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  2. Glycerol and potassium permanganate - Wikipedia

    en.wikipedia.org/wiki/Glycerol_and_potassium...

    The white smoke-like vapor produced by the reaction is a mixture of carbon dioxide gas and water vapor. Since the reaction is highly exothermic, initial sparking occurs, followed by a lilac- or pink-colored flame. [9] When energy or heat is added to electrons, their energy level increases to an excited state.

  3. Potassium permanganate - Wikipedia

    en.wikipedia.org/wiki/Potassium_permanganate

    The reagent is an alkaline solution of potassium permanganate. Reaction with double or triple bonds (R 2 C=CR 2 or R−C≡C−R) causes the color to fade from purplish-pink to brown. Aldehydes and formic acid (and formates) also give a positive test. [43] The test is antiquated. Baeyer's reagent reaction

  4. On-water reaction - Wikipedia

    en.wikipedia.org/wiki/On-water_reaction

    The reaction of quadricyclane with DEAD is a 2σ + 2σ + 2π cycloaddition that on water takes place within 10 minutes at room temperature with 82% yield. The same reaction in toluene takes 24 hours at 80 °C with 70% yield. An emulsion reaction in fluorinated cyclohexane takes 36 hours and the neat reaction takes even longer (48 hours).

  5. Permanganate - Wikipedia

    en.wikipedia.org/wiki/Permanganate

    A permanganate (/ p ər ˈ m æ ŋ ɡ ə n eɪ t, p ɜːr-/) [1] is a chemical compound with the manganate(VII) ion, MnO − 4, the conjugate base of permanganic acid.Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent.

  6. Water-reactive substances - Wikipedia

    en.wikipedia.org/wiki/Water-reactive_substances

    The Group 1 metal (M) is oxidised to its metal ions, and water is reduced to hydrogen gas (H 2) and hydroxide ion (OH −), giving a general equation of: 2 M(s) + 2 H 2 O(l) 2 M + (aq) + 2 OH − (aq) + H 2 (g) [8] The Group 1 metals or alkali metals become more reactive as their number of energy levels inceases.

  7. Heterogeneous water oxidation - Wikipedia

    en.wikipedia.org/wiki/Heterogeneous_Water_Oxidation

    Reduction 4H + + 4e − → 2H 2 E° = 0.00 V vs. NHE Overall 2H 2 O → 2H 2 + O 2 E°cell = +1.23 V; ΔG = 475 kJ/mol . Water splitting can be done at higher pH values as well however the standard potentials will vary according to the Nernst equation and therefore shift by -59 mV for each pH unit increase. However, the total cell potential ...

  8. Potassium manganate - Wikipedia

    en.wikipedia.org/wiki/Potassium_manganate

    This reaction illustrates the relatively rare role of hydroxide as a reducing agent. The concentration of K 2 MnO 4 in such solutions can be checked by measuring their absorbance at 610 nm. The one-electron reduction of permanganate to manganate can also be effected using iodide as the reducing agent: 2 KMnO 4 + 2 KI → 2 K 2 MnO 4 + I 2

  9. Chemical chameleon - Wikipedia

    en.wikipedia.org/wiki/Chemical_chameleon

    The chemical chameleon reaction shows the process in reverse, by reducing violet potassium permanganate first to green potassium manganate and eventually to brown manganese dioxide: [1] [2] [5] KMnO 4 (violet) → K 2 MnO 4 (green) → MnO 2 (brown/yellow suspension) Blue potassium hypomanganate may also form as an intermediate. [6]

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