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Hypophosphorous acid (HPA), or phosphinic acid, is a phosphorus oxyacid and a powerful reducing agent with molecular formula H 3 PO 2.It is a colorless low-melting compound, which is soluble in water, dioxane and alcohols.
The general formula of a phosphoric acid is H n+2−2x P n O 3n+1−x, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure, between 0 and n + 2 / 2 . Pyrophosphate anion. Trimethyl orthophosphate.
A common purification methods is liquid-liquid extraction, which involves the separation of phosphoric acids from water and other impurities using organic solvents, such as tributyl phosphate (TBP), methyl isobutyl ketone (MIBK), or n-octanol. Nanofiltration involves the use of a premodified nanofiltration membrane, which is functionalized by a ...
Hypophosphoric acid can be prepared by the reaction of red phosphorus with sodium chlorite at room temperature. [2]2 P + 2 NaClO 2 + 2 H 2 O → Na 2 H 2 P 2 O 6 + 2 HCl. A mixture of hypophosphoric acid, phosphorous acid (H 3 PO 3) and phosphoric acid (H 3 PO 4) is produced when white phosphorus oxidises in air when partially immersed in water.
Since only 0.5 mol of H 2 SO 4 are needed to neutralize 1 mol of OH −, the equivalence factor is: f eq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c(H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution.
Structural formula of Na 2 HPO 3.The anion has C 3v symmetry.. From the commercial perspective, the most important phosphite salt is basic lead phosphite.Many salts containing the phosphite ion have been investigated structurally, these include sodium phosphite pentahydrate (Na 2 HPO 3 ·5H 2 O).
Phosphorous acid (or phosphonic acid) is the compound described by the formula H 3 PO 3.This acid is diprotic (readily ionizes two protons), not triprotic as might be suggested by this formula.
NH 3 + 3 H 3 PO 3 + 3 CH 2 O → N(CH 2 PO 3 H 2) 3 + 3 H 2 O. Phosphonic acid also can be alkylated with acrylic acid derivatives to afford carboxyl functionalized phosphonic acids. This reaction is a variant of the Michael addition: CH 2 =CHCO 2 R + 3 H 3 PO 3 → (HO) 2 P(O)CH 2 CH 2 CO 2 R