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A photoswitch is a type of molecule that can change its structural geometry and chemical properties upon irradiation with electromagnetic radiation.Although often used interchangeably with the term molecular machine, a switch does not perform work upon a change in its shape whereas a machine does. [1]
The first example of an artificial molecular machine (AMM) was reported in 1994, featuring a rotaxane with a ring and two different possible binding sites. In 2016 the Nobel Prize in Chemistry was awarded to Jean-Pierre Sauvage, Sir J. Fraser Stoddart, and Bernard L. Feringa for the design and synthesis of molecular machines.
Molecular motors are natural (biological) or artificial molecular machines that are the essential agents of movement in living organisms. In general terms, a motor is a device that consumes energy in one form and converts it into motion or mechanical work ; for example, many protein -based molecular motors harness the chemical free energy ...
The term "Brownian motor" was originally invented by Swiss theoretical physicist Peter Hänggi in 1995. [3] The Brownian motor, like the phenomenon of Brownian motion that underpinned its underlying theory, was also named after 19th century Scottish botanist Robert Brown, who, while looking through a microscope at pollen of the plant Clarkia pulchella immersed in water, famously described the ...
Crystal structure of a molecular trefoil knot with two copper(I) templating ions bound within it reported by Sauvage and coworkers in Recl. Trav. Chim. Pay. B., 1993, 427–428. [ 2 ] Jean-Pierre Sauvage ( French pronunciation: [ʒɑ̃pjɛʁ sovaʒ] ; born 21 October 1944) is a French coordination chemist working at Strasbourg University .
Synthetic molecular motors are molecular machines capable of continuous directional rotation under an energy input. [2] Although the term "molecular motor" has traditionally referred to a naturally occurring protein that induces motion (via protein dynamics), some groups also use the term when referring to non-biological, non-peptide synthetic motors.
The activation strain model was originally proposed and has been extensively developed by Bickelhaupt and coworkers. [4] This model breaks the potential energy curve as a function of reaction coordinate, ζ, of a reaction into 2 components as shown in equation 1: the energy due to straining the original reactant molecules (∆E strain) and the energy due to interaction between reactant ...
Molecular machines a molecule that mimics the function of macroscopic machines. Subcategories. This category has only the following subcategory. M. Motor proteins (36 P)