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A colorful example is cobalt(II) chloride, which turns from blue to red upon hydration, and can therefore be used as a water indicator.. The notation "hydrated compound⋅n H 2 O", where n is the number of water molecules per formula unit of the salt, is commonly used to show that a salt is hydrated.
A salt with associated water of crystallization is known as a hydrate. The structure of hydrates can be quite elaborate, because of the existence of hydrogen bonds that define polymeric structures. [ 3 ] [ 4 ] Historically, the structures of many hydrates were unknown, and the dot in the formula of a hydrate was employed to specify the ...
NMR is the most informative technique for determining hydration numbers in solution. 1 H and 17 O NMR signals, even for paramagnetic species, can be interpreted to give information on hydration number.
Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO 3) 2 (H 2 O) x. The hydrates are hygroscopic blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. [5] [6] Common hydrates are the hemipentahydrate and trihydrate.
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO 4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry.
Only four of the six water molecules in the formula is bound to the nickel, and the remaining two are water of crystallization, so the formula of nickel(II) chloride hexahydrate is [NiCl 2 (H 2 O) 4]·2H 2 O. [9] Cobalt(II) chloride hexahydrate has a similar structure. The hexahydrate occurs in nature as the very rare mineral nickelbischofite.
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Cobalt(II) bromide can be prepared as a hydrate by the reaction of cobalt hydroxide with hydrobromic acid: . Co(OH) 2 + 2HBr → CoBr 2 ·6H 2 O The classical coordination compound bromopentaamminecobalt(III) bromide is prepared by oxidation of an aqueous solution of cobalt(II) bromide and ammonia.