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Photoacoustic spectroscopy is the measurement of the effect of absorbed electromagnetic energy (particularly of light) on matter by means of acoustic detection. The discovery of the photoacoustic effect dates to 1880 when Alexander Graham Bell showed that thin discs emitted sound when exposed to a beam of sunlight that was rapidly interrupted with a rotating slotted disk.
A tracer-gas leak testing method is a nondestructive testing method that detects gas leaks.A variety of methods with different sensitivities exist. Tracer-gas leak testing is used in the petrochemical industry, the automotive industry, the construction industry [1] and in the manufacture of semiconductors, among other uses.
Photoacoustic spectroscopy is also useful for the opposite case of opaque samples, where the absorption is essentially complete. In an arrangement where a sensor is placed in a gaseous phase above the sample and the light impinges the sample from above, the photoacoustic signal results from an absorption zone close to the surface.
Methods of detection include hydrostatic testing, tracer-gas leak testing, infrared, laser technology, and acoustic or sonar technologies. Some technologies are used only during initial pipeline installation and commissioning, while other technologies can be used for continuous monitoring during service.
Most fluorochromes are optimized for fluorescence emission and are sub-optimal for optoacoustic detection, because after absorbing the illuminating energy, they tend to emit fluorescence rather than convert it to heat and generate a photoecho. Dyes with higher absorption cross-sections generate stronger optoacoustic signals.
The first commercial application of photoionization detection was in 1973 as a hand-held instrument for the purpose of detecting leaks of VOCs, specifically vinyl chloride monomer (VCM), at a chemical manufacturing facility. The photoionization detector was applied to gas chromatography (GC) three years later, in 1976. [5]
Natural gas leaks happen nearly every day in the U.S. — and they can be deadly if they go undetected. A report from a group of Texas environmental nonprofits released in June found around 2,600 ...
In atmospheric chemistry, differential optical absorption spectroscopy (DOAS) is used to measure concentrations of trace gases. When combined with basic optical spectrometers such as prisms or diffraction gratings and automated, ground-based observation platforms, it presents a cheap and powerful means for the measurement of trace gas species ...
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