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Arrow pushing or electron pushing is a technique used to describe the progression of organic chemistry reaction mechanisms. [1] It was first developed by Sir Robert Robinson.In using arrow pushing, "curved arrows" or "curly arrows" are drawn on the structural formulae of reactants in a chemical equation to show the reaction mechanism.
A reaction mechanism shows how acetone reacts with methanol in acidic environment using curved arrow (electron or arrow pushing method) Mechanisms also are of interest in inorganic chemistry. A often quoted mechanistic experiment involved the reaction of the labile hexaaquo chromous reductant with the exchange inert pentammine cobalt(III) chloride.
In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...
Organic chemistry has a strong tradition of naming a specific reaction to its inventor or inventors and a long list of so-called named reactions exists, conservatively estimated at 1000. A very old named reaction is the Claisen rearrangement (1912) and a recent named reaction is the Bingel reaction (1993).
This article needs attention from an expert in chemistry. ... "First 25 of 125 big questions that face scientific inquiry over the next quarter-century".
Retrosynthetic analysis is a technique for solving problems in the planning of organic syntheses.This is achieved by transforming a target molecule into simpler precursor structures regardless of any potential reactivity/interaction with reagents.
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This means that the two half-lines that make a line are forced to have equal and opposite momentum. The line itself should be labelled by an arrow, drawn parallel to the line, and labeled by the momentum in the line k. The half-line at the tail end of the arrow carries momentum k, while the half-line at the head-end carries momentum −k.