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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
Trimethyl borate is a popular borate ester used in organic synthesis. Borate esters form spontaneously when treated with diols such as sugars and the reaction with mannitol forms the basis of a titrimetric analytical method for boric acid. Metaborate esters show considerable Lewis acidity and can initiate epoxide polymerization reactions. [4]
Borate anions are largely in the form of the undissociated acid in aqueous solution at physiological pH. No further metabolism occurs in either animals or plants. In animals, boric acid/borate salts are essentially completely absorbed following oral ingestion. Absorption occurs via inhalation, although quantitative data are unavailable.
TBE or Tris/Borate/EDTA, is a buffer solution containing a mixture of Tris base, boric acid and EDTA. In molecular biology, TBE and TAE buffers are often used in procedures involving nucleic acids , the most common being electrophoresis .
When orthoborate salts are dissolved in water, the anion converts mostly to boric acid B(OH) 3 and other hydrogen-containing borate anions, mainly tetrahydroxyborate [B(OH) 4] −. The reactions of orthoborate in solution are therefore mostly those of these compounds.
It is one of the boron oxoacids, that is, a borate. The name is also applied to the hydrated ion [B 4 O 5 (OH) 4] 2− as present in borax. The ion occurs in boric acid solutions at neutral pH, being formed by condensation of orthoborate and tetrahydroxyborate anions: 2 B(OH) 3 + 2 [B(OH) 4] − ⇌ [B 4 O 5 (OH) 4] − 2 + 5 H 2 O
Potassium fluoroborate is obtained by treating potassium carbonate with boric acid and hydrofluoric acid. B(OH) 3 + 4 HF → HBF 4 + 3 H 2 O 2 HBF 4 + K 2 CO 3 → 2 KBF 4 + H 2 CO 3. Fluoroborates of alkali metals and ammonium ions crystallize as water-soluble hydrates with the exception of potassium, rubidium, and cesium.
Calcium borate (Ca 3 (BO 3) 2). It can be prepared by reacting calcium metal with boric acid. The resulting precipitate is calcium borate. A hydrated form occurs naturally as the minerals colemanite, nobleite and priceite. [citation needed] One of its uses is as a binder in some grades of hexagonal boron nitride for hot pressing.
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