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These sites or holes can be filled with other atoms (interstitial defect). The picture with packed circles is only a 2D representation. In a crystal lattice, the atoms (spheres) would be packed in a 3D arrangement. This results in different shaped interstitial sites depending on the arrangement of the atoms in the lattice.
In BCC metals, interstitial sites of an unstrained lattice are equally favorable. The interstitial solutes create elastic dipoles. [14] However, once a strain is applied on the lattice, such as that formed by a dislocation, 1/3 of the sites become more favorable than the other 2/3.
Interstitial atoms (blue) occupy some of the spaces within a lattice of larger atoms (red) In materials science, an interstitial defect is a type of point crystallographic defect where an atom of the same or of a different type, occupies an interstitial site in the crystal structure.
[4] [5] The bcc and fcc, with their higher densities, are both quite common in nature. Examples of bcc include iron, chromium, tungsten, and niobium. Examples of fcc include aluminium, copper, gold and silver. Another important cubic crystal structure is the diamond cubic structure, which can appear in carbon, silicon, germanium, and tin.
A nearby pair of a vacancy and an interstitial is often called a Frenkel defect or Frenkel pair. This is caused when an ion moves into an interstitial site and creates a vacancy. Due to fundamental limitations of material purification methods, materials are never 100% pure, which by definition induces defects in crystal structure.
Interstitial sites refer to the empty spaces in between the atoms in the crystal lattice. These spaces can be filled by oppositely charged ions to form multi-element structures. They can also be filled by impurity atoms or self-interstitials to form interstitial defects .
For multiple-component structures (such as with interstitial alloys), the APF can exceed 0.74. The atomic packing factor of a unit cell is relevant to the study of materials science , where it explains many properties of materials.
The (finite) list of all symmetry operations which leave the given point invariant taken together make up another group, which is known as the site symmetry group of that point. [4] By definition, all points with the same site symmetry group, or a conjugate site symmetry group, are assigned the same Wyckoff position.