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Band diagram for Schottky barrier at equilibrium Band diagram for semiconductor heterojunction at equilibrium. In solid-state physics of semiconductors, a band diagram is a diagram plotting various key electron energy levels (Fermi level and nearby energy band edges) as a function of some spatial dimension, which is often denoted x. [1]
In some materials, for example, in graphene and zigzag graphene quantum dot, there exists the energy states having energy eigenvalues exactly equal to zero (E=0) besides the conduction and valence bands. These states are called edge states which modifies the electronic and optical properties of the materials significantly. [3] [4] [5] [6]
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states.
To understand how band structure changes relative to the Fermi level in real space, a band structure plot is often first simplified in the form of a band diagram. In a band diagram the vertical axis is energy while the horizontal axis represents real space. Horizontal lines represent energy levels, while blocks represent energy bands.
Band edge diagram of a basic HEMT. Conduction band edge E C and Fermi level E F determine the electron density in the 2DEG. Quantized levels form in the triangular well (yellow region) and optimally only one of them lies below E F. Heterostructure corresponding to the band edge diagram above.
The band gap (usually given the symbol ) gives the energy difference between the lower edge of the conduction band and the upper edge of the valence band. Each semiconductor has different electron affinity and band gap values. For semiconductor alloys it may be necessary to use Vegard's law to calculate these values.
Figure 1. (a) Shows an energy diagram of n-type semiconductor in contact with redox electrolyte at the left side (yellow), and with a metallic ohmic contact at the right side. E c is the conduction band edge energy, E v is the valence band energy of the semiconductor.
In semiconductors, the band gap of a semiconductor can be of two basic types, a direct band gap or an indirect band gap. The minimal-energy state in the conduction band and the maximal-energy state in the valence band are each characterized by a certain crystal momentum (k-vector) in the Brillouin zone. If the k-vectors are different, the ...