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The kinetic theory of gases deals not only with gases in thermodynamic equilibrium, but also very importantly with gases not in thermodynamic equilibrium. This means using Kinetic Theory to consider what are known as "transport properties", such as viscosity, thermal conductivity, mass diffusivity and thermal diffusion.
Kinetic theory may refer to: Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of ...
A gas is said to be in local equilibrium if it satisfies this equation. [4] The assumption of local equilibrium leads directly to the Euler equations, which describe fluids without dissipation, i.e. with thermal conductivity and viscosity equal to . The primary goal of Chapman–Enskog theory is to systematically obtain generalizations of the ...
The law can also be derived theoretically based on the presumed existence of atoms and molecules and assumptions about motion and perfectly elastic collisions (see kinetic theory of gases). These assumptions were met with enormous resistance in the positivist scientific community at the time, however, as they were seen as purely theoretical ...
In the kinetic theory of gases in physics, the molecular chaos hypothesis (also called Stosszahlansatz in the writings of Paul and Tatiana Ehrenfest [1] [2]) is the assumption that the velocities of colliding particles are uncorrelated, and independent of position.
[4] [5] Bernoulli's principle can be derived from the principle of conservation of energy. This states that, in a steady flow, the sum of all forms of energy in a fluid is the same at all points that are free of viscous forces. This requires that the sum of kinetic energy, potential energy and internal energy remains constant.
Perrin was awarded the Nobel Prize in Physics in 1926 "for his work on the discontinuous structure of matter". [4] The many-body interactions that yield the Brownian pattern cannot be solved by a model accounting for every involved molecule. Consequently, only probabilistic models applied to molecular populations can be employed to describe it. [5]
In physics (specifically, the kinetic theory of gases), the Einstein relation is a previously unexpected [clarification needed] connection revealed independently by William Sutherland in 1904, [1] [2] [3] Albert Einstein in 1905, [4] and by Marian Smoluchowski in 1906 [5] in their works on Brownian motion.